Polyoxometalates are a rapidly growing class of discrete metal oxide clusters with a wide range of applications including functional materials. These anionic clusters of the group V and VI transition metals are inexpensive and non-toxic. Within group V polyoxometalates, niobium and tantalum chemistry has been underdeveloped owing to their unique...
Small-angle X-ray scattering (SAXS) studies of aqueous [Ta₆O₁₉]⁸⁻
compared to prior studies of aqueous [Nb₆O₁₉]⁸⁻ reveals key
differences in behaviour, which is likely at the root of the difficultly
in developing polyoxotantalate chemistry. Specifically, where
contact ion-pairing dominates between [Nb₆O₁₉]⁸⁻ and its
counterions, solvent-separated ion-pairing between [Ta₆O₁₉]⁸⁻
and its counterions...
Polyoxoniobates are exceptional amongst polyoxometalates in that
they can potentially perform base catalysis in water, a process in
which a proton is bonded to an oxo ligand, and a hydroxyl is
released. Catalytic decomposition of chemical warfare agents such
as organofluorophosphates that were used recently in the infamous
civilian attacks...
Lauren Fath, in her non-fiction collection Half-Life: Essays, examines the underpinnings of her upbringing in suburban Fort Wayne, Indiana, focusing primarily on familial relationships and the importance of hindsight in understanding how our families make an imprint on our lives. By looking at our relationships through the lens offered by...
Patterns of primary productivity in the Arctic are expected to change with continued warming, yet productivity measurements are historically limited, both spatially and temporally. An established method of measuring net biological oxygen production, which can be used to estimate net community production (NCP) rates, is with an equilibrated inlet mass...
The Pacific Arctic is undergoing rapid biogeochemical changes in response to warming air temperatures caused by climate forcing. This is manifesting as changes in seasonal sea ice thickness and sea ice extent, as well as changes in primary production within surface waters. The data and samples analyzed here were collected...
Recent studies in men have shown plasma levels of vitamin B-6
and pyridoxal 5'-phosphate (PLP), the active form of vitamin B-6, to
increase with exercise. It was hypothesized that muscle glycogen
phosphorylase might be the source of these increases as this enzyme
has been shown to increase with increasing vitamin...
Purpose: This study examines the relationship between community-based fitness class participation and risk for falls in adults aged 55 or older. Our aim was to compare scores on fall risk factors between community-based Better Bones & Balance® (BBB) participants and active peers who engage in other (non-BBB) community-based fitness classes....