A Langmuir sorption model incorporating a second step of
irreversible absorption was applied to a model soil system. The column
was packed with cellulose triacetate; pulse and step input tests with
3,4-dichlorophenol were performed; the effluent concentration was
measured by electron capture detector gas chromatography and sorption
rate constants were...
Hydrogen has been shown to be a promising replacement for fossil fuels for use in light duty vehicles because it is a clean, renewable and plentiful resource with a high gravimetric energy density. However, in order to obtain an acceptable volumetric energy density, densification of the hydrogen is required. Adsorptive...
Prevention of groundwater contamination by agricultural
chemicals requires an understanding of the complex
processes that control pesticide movement below the soil
surface. Through this understanding it is possible to try
to predict which areas may be most vulnerable to
contamination. The many models that have been developed to
characterize pesticide...
A multiple stage crosscurrent packed column suitable for gas-liquid
mass transfer was constructed and operated. The absorption
column consisted of a rectangular box constructed of plexiglass and
metal. Deflection baffles were positioned at regular intervals on
opposite sides of a central packed section to divert the gas phase
into the...
Studies were undertaken of the adsorption of chlorinated phenols from aqueous solution on granular activated carbon (Filtrasorb-400, 30x40 mesh). Single-component equilibrium adsorption data on the eight compounds in two concentration ranges at pH 7.0 fit the Langmuir equation better than the Freundlich equation. The adsorptive capacities at pH 7.0 increase...
A multi-stage, crosscurrent column, packed with Pall rings, was
employed for oxygen absorption from an oxygen-rich air phase by
contacting with water. Mass transfer data were collected for the
column using 6 and 12 baffles and employing a partial gas phase recycle.
Data were also collected from a countercurrent column...