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  • Exploring the Distinct Solution Behavior of Isostructural Polycoltanates

    Creator:
    Fullmer, Lauren
    Abstract:
    Polyoxometalates are a rapidly growing class of discrete metal oxide clusters with a wide range of applications including functional materials. These anionic clusters of the group V and VI transition metals are inexpensive and non-toxic. Within group V polyoxometalates, niobium and tantalum chemistry has been underdeveloped owing to their unique...
    Resource Type:
    Dissertation
    Full Text:
    AN ABSTRACT OF THE DISSERTATION OF Lauren Fullmer for

  • FullmerLaurenChemistryContrastingIonAssociation.pdf

    Creator:
    Fullmer, Lauren B., Molina, Pedro I., Antonio, Mark R., and Nyman, May
    Abstract:
    Small-angle X-ray scattering (SAXS) studies of aqueous [Ta₆O₁₉]⁸⁻ compared to prior studies of aqueous [Nb₆O₁₉]⁸⁻ reveals key differences in behaviour, which is likely at the root of the difficultly in developing polyoxotantalate chemistry. Specifically, where contact ion-pairing dominates between [Nb₆O₁₉]⁸⁻ and its counterions, solvent-separated ion-pairing between [Ta₆O₁₉]⁸⁻ and its counterions...
    Full Text:
    behaviour of Ta and Nb polyoxometalates† Lauren B. Fullmer,a Pedro I. Molina,a Mark R. Antoniob and May

  • FullmerLaurenChemistryContrastingIonAssociation_SupportingInformation.pdf

    Creator:
    Fullmer, Lauren B., Molina, Pedro I., Antonio, Mark R., and Nyman, May
    Abstract:
    Small-angle X-ray scattering (SAXS) studies of aqueous [Ta₆O₁₉]⁸⁻ compared to prior studies of aqueous [Nb₆O₁₉]⁸⁻ reveals key differences in behaviour, which is likely at the root of the difficultly in developing polyoxotantalate chemistry. Specifically, where contact ion-pairing dominates between [Nb₆O₁₉]⁸⁻ and its counterions, solvent-separated ion-pairing between [Ta₆O₁₉]⁸⁻ and its counterions...
    Full Text:
    -association Behaviour of Ta and Nb Polyoxometalates Lauren. B. Fullmer,a Pedro. I. Molina,a Mark R. Antoniob

  • Contrasting ion-association behaviour of Ta and Nb polyoxometalates

    Creator:
    Fullmer, Lauren B., Molina, Pedro I., Antonio, Mark R., and Nyman, May
    Abstract:
    Small-angle X-ray scattering (SAXS) studies of aqueous [Ta₆O₁₉]⁸⁻ compared to prior studies of aqueous [Nb₆O₁₉]⁸⁻ reveals key differences in behaviour, which is likely at the root of the difficultly in developing polyoxotantalate chemistry. Specifically, where contact ion-pairing dominates between [Nb₆O₁₉]⁸⁻ and its counterions, solvent-separated ion-pairing between [Ta₆O₁₉]⁸⁻ and its counterions...
    Resource Type:
    Article

  • Nerve Agent Degradation Using Polyoxoniobates

    Creator:
    Kinnan, Mark K., Creasy, William R., Fullmer, Lauren B., Schreuder-Gibson, Heidi L., and Nyman, May
    Abstract:
    Polyoxoniobates are exceptional amongst polyoxometalates in that they can potentially perform base catalysis in water, a process in which a proton is bonded to an oxo ligand, and a hydroxyl is released. Catalytic decomposition of chemical warfare agents such as organofluorophosphates that were used recently in the infamous civilian attacks...
    Resource Type:
    Article
    Full Text:
    Degradation Using Polyoxoniobates Mark K. Kinnan,[a] William R. Creasy,[b] Lauren B. Fullmer, [c] Heidi L

  • Half-life : essays

    Creator:
    Fath, Lauren
    Abstract:
    Lauren Fath, in her non-fiction collection Half-Life: Essays, examines the underpinnings of her upbringing in suburban Fort Wayne, Indiana, focusing primarily on familial relationships and the importance of hindsight in understanding how our families make an imprint on our lives. By looking at our relationships through the lens offered by...
    Resource Type:
    Masters Thesis
    Full Text:
    AN ABSTRACT OF THE THESIS OF Lauren Fath for the degree of

  • Lauren OsbornFinal Thesis6 8 2007.pdf

    Creator:
    Osborn, Lauren A.
    Abstract:
    Collaboration is crucial when advancing in scientific research. One person cannot study all aspects of a system. That is why it is important for the scientific community to communicate with each other and stay updated on research being conducted in other labs around the world. In my research, I was...
    Full Text:
    1V 1/ v2 v2 V 1v 1/ v2 v2 v1 v1 /v 2v 2 Genotype F in a l L e a f N u m b e r

  • High-resolution Biological Net Community Production in the Pacific-influenced Arctic: A Multi-method Comparison

    Creator:
    Cynar, Haley
    Abstract:
    Patterns of primary productivity in the Arctic are expected to change with continued warming, yet productivity measurements are historically limited, both spatially and temporally. An established method of measuring net biological oxygen production, which can be used to estimate net community production (NCP) rates, is with an equilibrated inlet mass...
    Resource Type:
    Masters Thesis
    Full Text:
    Comparison Abstract approved: _____________________________________________________ Lauren Juranek

  • A Multivariate Analysis of Pacific Arctic Surface Waters

    Creator:
    Bryant, Aleesa
    Abstract:
    The Pacific Arctic is undergoing rapid biogeochemical changes in response to warming air temperatures caused by climate forcing. This is manifesting as changes in seasonal sea ice thickness and sea ice extent, as well as changes in primary production within surface waters. The data and samples analyzed here were collected...
    Resource Type:
    Capstone Project
    Full Text:
    )(a), southbound temperature (b), northbound salinity (c) and northbound salinity (d). Northbound

  • Influence of controlled strenuous exercise on vitamin B-6 metabolism in man : effects of carbohydrate depletion-repletion diets and vitamin B-6 supplements

    Creator:
    Hatcher, Lauren Francis
    Abstract:
    Recent studies in men have shown plasma levels of vitamin B-6 and pyridoxal 5'-phosphate (PLP), the active form of vitamin B-6, to increase with exercise. It was hypothesized that muscle glycogen phosphorylase might be the source of these increases as this enzyme has been shown to increase with increasing vitamin...
    Resource Type:
    Masters Thesis
    Full Text:
    AN ABSTRACT OF THE THESIS OF Lauren Francis Hatcher for the