This thesis explores open questions regarding molecular forms and interactions of natural and synthetic aromatic compounds present in soils and sediments.
Plant biomass-derived black carbon (biochar) generated through incomplete natural and anthropogenic combustion processes is a major source of aromaticity in terrestrial ecosystems. Chapter one represents a detailed account of...
Intimate associations with reactive metal species permanently protect soil organic matter (SOM) from microbial access and oxidation, contributing to the build-up of organic carbon (C) stocks in soils. It is increasingly recognized, however, that such associations can be reversible and that reactive metal species might even facilitate the oxidation of...
Soils and sediments worldwide contain appreciable amounts of thermally altered organic matter (chars) of both natural and industrial origin. Additions of chars into soils are discussed as a strategy to mitigate climate change. Chars contain electroactive quinoid functional groups and polycondensed aromatic sheets that were recently shown to be of...
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plant biomass-derived char black carbon (biochar) 3
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Laura Klüpfel†, MarcoKeiluweit§,‡, Markus
Understanding the processes controlling organic matter (OM) stocks in upland soils, and the ability to management them, is crucial for maintaining soil fertility and carbon (C) storage as well as projecting change with time. OM inputs are balanced by the mineralization (oxidation) rate, with the difference determining whether the system...
Soils and sediments worldwide contain appreciable amounts of thermally altered organic matter (chars) of both natural and industrial origin. Additions of chars into soils are discussed as a strategy to mitigate climate change. Chars contain electroactive quinoid functional groups and polycondensed aromatic sheets that were recently shown to be of...
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†, MarcoKeiluweit§,‡, Markus Kleber§,¶ , and Michael Sander†,* 5
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† Department of Environmental
Soils and sediments worldwide contain appreciable amounts of thermally altered organic matter (chars) of both natural and industrial origin. Additions of chars into soils are discussed as a strategy to mitigate climate change. Chars contain electroactive quinoid functional groups and polycondensed aromatic sheets that were recently shown to be of...
Litter decomposition is a keystone ecosystem process impacting nutrient cycling and productivity, soil properties, and the terrestrial carbon (C) balance, but the factors regulating decomposition rate are still poorly understood. Traditional models assume that the rate is controlled by litter quality, relying on parameters such as lignin content as predictors....
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manganese redox cycling
Long-term litter decomposition controlled by manganese redox cycling
Keiluweit, M
Litter decomposition is a keystone ecosystem process impacting nutrient cycling and productivity, soil properties, and the terrestrial carbon (C) balance, but the factors regulating decomposition rate are still poorly understood. Traditional models assume that the rate is controlled by litter quality, relying on parameters such as lignin content as predictors....
Full Text:
pnasSI201508945 1..5
Supporting Information
Keiluweit et al
The aromatic carbon structure is a defining property of chars and is often expressed with the help of two
concepts: (i) aromaticity and (ii) degree of aromatic condensation. The varying extent of these two features
is assumed to largely determine the relatively high persistence of charred material in the environment...
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, MarcoKeiluweit c, Markus Kleber c,d,
Caroline A. Masiello e, Anna V. McBeath f, Peter S. Nico g, Lacey
The aromatic carbon structure is a defining property of chars and is often expressed with the help of two
concepts: (i) aromaticity and (ii) degree of aromatic condensation. The varying extent of these two features
is assumed to largely determine the relatively high persistence of charred material in the environment...
Full Text:
Keiluweit et
S2
al. (2010). Increase in absorbance of aromatic C=C (285 eV) relative to oxygenated