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  • Chemical Solution Deposition and in-situ Structural Characterization of Pb-free, Bi-based, Piezoelectric Thin Films

    Creator:
    Fox, Austin J.
    Abstract:
    This work explores the electric field induced strain mechanisms in environmentally benign Bi0.5Na0.5TiO3 (BNT) based piezoelectric thin films. Although BNT-based materials show promise as replacements for toxic Pb-based piezoelectrics, the displacement mechanisms are not consistent between thin films and bulk materials, and the differences have yet to be well understood....
    Resource Type:
    Dissertation
    Full Text:
    : Chemical Solution Deposition and in-situ Structural Characterization of Pb- free, Bi-based, Piezoelectric

  • Development of perovskite thin films for use in piezoelectric based microelectromechanical systems

    Creator:
    Shelton, Christopher T.
    Abstract:
    The lead-zirconate-titanate (PZT) solid solution system is currently the workhorse of piezoelectric-based microelectromechanical systems (MEMS) research. Among bulk materials it is known to be one of the strongest piezoelectrics, with extremely high piezoelectric coefficients and electro-mechanical coupling factors. Reproducing these exceptional qualities in thin film form, however, requires precise tuning...
    Resource Type:
    Masters Thesis
    Full Text:
    coercive field (Ec). Remnant polarization is strongly correlated with piezoelectric response; a material

  • Development of bi-based lead-free piezoelectric materials : thin film piezoelectric materials via PVD and CSD routes

    Creator:
    Jeon, Yu Hong
    Abstract:
    Piezoelectric materials have been widely used in electromechanical actuators, sensors, and ultrasonic transducers. Among these materials, lead zirconate titanate Pb(Zr[subscript 1‐x]Ti[subscript x])O₃ (PZT) has been primarily investigated due to its excellent piezoelectric properties. However, environmental concerns due to the toxicity of PbO have led to investigations into alternative materials systems....
    Resource Type:
    Dissertation
    Full Text:
    ,
2012.
 Title:
Development
of
Bi‐based
Lead‐free
Piezoelectric
Materials:
Thin
Film
 Piezoelectric

  • Non-Stoichiometry in Bismuth Perovskite Solid Solutions

    Creator:
    Prasertpalichat, Sasiporn
    Abstract:
    The role of A-site non-stoichiometry was investigated in lead-free piezoelectric ceramics based on compositions in the 1-x(Bi₀.₅Na₀.₅TiO₃)-xBaTiO₃ system near the morphotropic phase boundary where x = 0.055, 0.06 and 0.07. The samples were prepared by a conventional solid state mixed oxide route with the A- site stoichiometry modified to incorporate...
    Resource Type:
    Dissertation
    Full Text:
    piezoelectric ceramics based on compositions in the 1-x(Bi0.5Na0.5TiO3)-xBaTiO3 system near the morphotropic

  • Development of new high-temperature piezoelectric perovskite ceramics

    Creator:
    Ansell, Troy Youngmin
    Abstract:
    Lead zirconate titanate (PZT) is the dominant ferroelectric material in the market due to its excellent piezoelectric properties, relatively high Curie transition temperature (T[subscript C]), low cost, etc. However, because of emerging applications with requirements for high temperature (T[subscript C] > 400 °C) ferroelectrics, researchers are increasingly looking at alternative...
    Resource Type:
    Dissertation
    Full Text:
    : Development of New High-Temperature Piezoelectric Perovskite Ceramics Abstract approved: David P. Cann Lead

  • Defect Mechanisms in Bismuth-based Perovskites

    Creator:
    Kumar, Nitish
    Abstract:
    The aim of this research is to develop a fundamental understanding of the dominant defect species and the relevant defect equilibrium conditions for bismuth-containing perovskites to help guide the development of these materials for emerging applications. This is of paramount importance for many demanding applications, because ultimately the defect equilibria...
    Resource Type:
    Dissertation
    Full Text:
    influence on phenomena such as piezoelectric fatigue, reliability, and leakage current. At the same time