Electron capture negative ion mass spectroscopy (ECNIMS) has been
performed on environmental chemicals and explosives. A trochoidal electron
monochromator interfaced to a gas chromatograph and a quadrupole mass
spectrometer allows compounds to be studied by this method. The method employed
here differs from standard ECNIMS in that no reagent gas...
The end of the Cold War brought about changes within international political relations that resulted in expanded interest in global civil society. Such developments, like globalization and democratization, have encouraged the growth of social and political organizations. Political scientists have found that these inter-governmental and non-governmental organizations have a significant...
Streams and rivers play a critical role in global carbon (C) cycling by processing, storing, and transporting C. Headwater streams which make up more than 95% of the length of streams and rivers worldwide have disproportionate influence on fluvial C dynamics. The hyporheic zone (HZ) of headwater streams is a...
In this dissertation, I examine emerging economic issues which intersect outdoor recreation, environmental quality, public land use, and public health advisories. First, I explore the potential impacts of social media on visitation to public land. Social media, and in particular Instagram, has been suggested by journalist and land managers as...
Developed coastlines provide a variety of recreation opportunities to coastal residents and visitors but are also the first line of defense for oceanfront development against chronic hazards like erosion and sea level rise. In the Pacific Northwest of the United States, oceanfront homes also face an additional severe but very...
2,5-dihydroxyacetanilide epoxidase from Streptomyces LL-C10037 (DHAE I)
catalyzes the epoxidation of hydroquinone 4, to form epoxyquinone 7. DHAE I has been
purified to homogeneity, with an overall purification factor greater than 23,000. N-terminal
and internal amino acid sequences have been obtained from the purified enzyme so
that the epoxidase gene...
The level of polymorphisms of many biochemical and DNA markers are low in
cultivated sunflower (Helianthus annuus L.). The number of mapped public DNA
markers is limited. Molecular markers have not been developed for the most
important diseases of sunflower, such as downy mildew. The objectives of this
study were...
The loss of all deuterium labels from previous feedings of [2-²H]-,
[3,3-²H₂]-, and [2,3,3-²H₃]arginines had indicated the possible intermediacy
of β-hydroxy- and β-ketoarginine (30 and 31, respectively) in the
biosynthesis of the streptolidine portion of streptothricin F (la).
In order to confirm or refute this evidence, D,L-[2,3,3,5,5-²H₅]-
arginine (32) was...
Wildtype sunflower typically produces 12-24% oleic acid (18:1) and 70-82%
linoleic acid (18:2). High-oleic sunflower, by contrast, produces up to 80-94% oleic
acid. The monounsaturated oleic acid has a greater oxidative stability than the
polyunsaturated linoleic acid, predominant in wildtype sunflower, and has greater
nutritional benefits than polyunsaturated and saturated...