Graduate Thesis Or Dissertation
 

Dilute solution molecular characterization and drag reducation studies of high molecular weight polyethylene oxide

Public Deposited

Downloadable Content

Download PDF
https://ir.library.oregonstate.edu/concern/graduate_thesis_or_dissertations/f1881q352

Descriptions

Attribute NameValues
Creator
Abstract
  • The molecular weight distributions of two high molecular weight (M[subscript w]>>1 million) polyethylene polymers, WSR-308 and WSR-301, were characterized with gel permeation chromatography (GPC) coupled with a multi-angle laser light scattering detector (MALLS). The M[subscript w] of the WSR-308 was found to be 5.10x10⁶ g/mol with a molecular weight range from about 1 million g/mol to as high as 10 million g/mol. The M[subscript w] of the WSR-301 was found to be 3.16x10⁶ g/mol with the lowest molecular weight about 400,000 g/mol while the highest molecular weight component may have been as high as 8 million g/mol. Attempts to measure the M[subscript w] of the two polymers using static light scattering (SLS) techniques proved to be difficult. In conjunction with these studies, drag reduction and shear degradation studies of the two polymers in water were also conducted. Solutions of the two polymers, ranging from 1 to 10 ppm including mixtures of the two, were tested in a pipe-flow apparatus to obtain friction factor and %DR data. In every case, the greater the concentration and/or the molecular weight of the polymer, the greater the drag reduction effects. Additionally, the higher molecular weight polymer and mixtures with a greater weight percentage of the higher molecular weight polymer were found to shear degrade less quickly than otherwise. A unique point along the maximum drag reduction asymptote (MDA) termed the "divergence point" was a focus of this study and an energy model based on frictional losses correlates well to the data. The correlation developed here relates the difference in frictional losses between the solvent by itself and the polymer solution directly to the mass concentration and molecular weight of the polymer. This frictional difference was proportional to the product of the mass concentration and molecular weight where both quantities were to approximately the first power.
Resource Type
Date Available
Date Issued
Degree Level
Degree Name
Degree Field
Degree Grantor
Commencement Year
Advisor
Academic Affiliation
Non-Academic Affiliation
Subject
Rights Statement
Publisher
Peer Reviewed
Language
Digitization Specifications
  • File scanned at 300 ppi (Monochrome, 256 Grayscale) using Capture Perfect 3.0.82 on a Canon DR-9080C in PDF format. CVista PdfCompressor 4.0 was used for pdf compression and textual OCR.
Replaces

Relationships

Parents:

This work has no parents.

In Collection:

Items

Thumbnail Title Date Uploaded Visibility Actions
file details JonesBrianDion2002.pdf 2017-08-19 Public Download