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| dc.creator | Yang, Hua | |
| dc.creator | Banerjee, Somdev | |
| dc.creator | Carter, Rich G. | |
| dc.date.accessioned | 2012-08-06T16:34:28Z | |
| dc.date.issued | 2012-07-07 | |
| dc.identifier.citation | Yang, H., Banerjee, S., & Carter, R. G. (2012). Proline sulphonamide-catalysed yamada-otani condensation: Reaction development, substrate scope and scaffold reactivity. Organic & Biomolecular Chemistry, 10(25), 4851. | en_US |
| dc.identifier.uri | http://hdl.handle.net/1957/31866 | |
| dc.description | This is the publisher’s final pdf. The published article is copyrighted by The Royal Society of Chemistry and can be found at: www.rsc.org/obc. | en_US |
| dc.description.abstract | The development of a proline sulphonamide-catalysed method for enantioselective and diastereoselective construction of functionalized cyclohexenones is described. Impact of catalyst structure as well as solvent effects and additives are explored. A significant substrate scope is demonstrated by variation of both the aldehyde and the enone components. Diastereoselective derivatization of the cyclohexenone scaffold illustrates its utility as a building block for chemical synthesis. | en_US |
| dc.description.sponsorship | Financial support was provided by the Oregon State University (OSU) Venture Fund and the National Science Foundation (CHE-0848704). The National Science Foundation (CHE-0722319) and the Murdock Charitable Trust (2005265) are acknowledged for their support of the NMR facility. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | The Royal Society of Chemistry | en_US |
| dc.relation.ispartofseries | Organic & Biomolecular Chemistry | en_US |
| dc.relation.ispartofseries | Vol. 10 no. 25 | en_US |
| dc.subject | Alpha | en_US |
| dc.subject | Beta unsaturated ketones | en_US |
| dc.subject | Enantioselective construction | en_US |
| dc.subject | Quaternary stereocenters | en_US |
| dc.subject | Asymmetric synthesis | en_US |
| dc.subject | Addition reactions | en_US |
| dc.subject | Mannich reactions | en_US |
| dc.subject | Alder reactions | en_US |
| dc.subject | Michael | en_US |
| dc.subject | Carbon | en_US |
| dc.subject | Cyclohexenones | en_US |
| dc.title | Proline sulphonamide-catalysed Yamada–Otani condensation: reaction development, substrate scope and scaffold reactivity | en_US |
| dc.type | Article | en_US |
| dc.identifier.doi | 10.1039/c2ob25400j | |
| dc.date.embargo | 2013-07-08 | |
| dc.description.embargo | 2013-07-08 | |
| dc.description.embargopolicy | Repository Administrators | en |
