Article
 

Contrasting ion-association behaviour of Ta and Nb polyoxometalates

Public Deposited

Downloadable Content

Download PDF
https://ir.library.oregonstate.edu/concern/articles/cj82k922d

Descriptions

Attribute NameValues
Creator
Abstract
  • Small-angle X-ray scattering (SAXS) studies of aqueous [Ta₆O₁₉]⁸⁻ compared to prior studies of aqueous [Nb₆O₁₉]⁸⁻ reveals key differences in behaviour, which is likely at the root of the difficultly in developing polyoxotantalate chemistry. Specifically, where contact ion-pairing dominates between [Nb₆O₁₉]⁸⁻ and its counterions, solvent-separated ion-pairing between [Ta₆O₁₉]⁸⁻ and its counterions has been unveiled in the current study.
Resource Type
DOI
Date Available
Date Issued
Citation
  • Fullmer, L. B., Molina, P. I., Antonio, M. R., & Nyman, M. (2014). Contrasting ion-association behaviour of Ta and Nb polyoxometalates. Dalton Transactions, 43(41), 15295-15299. doi:10.1039/C4DT02394C
Journal Title
Journal Volume
  • 43
Journal Issue/Number
  • 41
Rights Statement
Funding Statement (additional comments about funding)
  • The work at Oregon State University was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering under Award # DE-SC0010802TDD. The work at Argonne National Laboratory—including the use of the Advanced Photon Source, an Office of Science User Facility operated for the U.S. Department of Energy (DOE) Office of Science by Argonne National Laboratory—was supported by the U.S. DOE under Contract No. DE-AC02-06CH11357.
Publisher
Peer Reviewed
Language
Replaces

Relationships

Parents:

This work has no parents.

Items

Thumbnail Title Date Uploaded Visibility Actions
file details FullmerLaurenChemistryContrastingIonAssociation.pdf 07/26/2017 Public
file details FullmerLaurenChemistryContrastingIonAssociation_SupportingInformation.pdf 07/26/2017 Public