Abstract:
Evaluations of previously established field trials indicate that
chioropicrin and Vorlex continue to provide a diminishing level of protection to
Douglas-fir poles. Tests of solid methylisothiocyanate (MITC), now in their
thirteenth year, indicate that this chemical continues to prevent recolonization
of Douglas-fir poles by decay fungi. MITC appears to provide equivalent or
better protection than Vorlex.
Gelatin encapsulated MITC and chioropicrin also continue to perform well
in field trials. Although the gelatin is water soluble and must decompose to
release the chemical, the addition of water to the treatment holes did not appear
to significantly enhance long-term MITC performance.
Laboratory trials to identify safer fumigants indicate that sodium nmethyldithiocarbamate
decomposition occurs even in dry wood, although the rate
of decomposition is enhanced by the presence of some moisture. A gelled 40 %
NaMDC formulation has also been evaluated for its ability to eliminate decay
fungi from Douglas-fir heartwood. This formulation has performed better than
liquid metham sodium. Field trials are planned with both the solid and gelled
NaMDC.
Laboratory trials have also been performed to evaluate the toxicity of
fused borate rods to Antrodia carbonica and Postia placenta. These two fungi are
important decayers of Douglas-fir utility poles. The results indicate that the
boron moved well through both wood species, but complete elimination of the test
fungus required 6 to 8 weeks. Antrodia carbonica was generally more tolerant of
boron than P. placenta. Field trials of fused borate rods indicate that the
boron has moved downward from the point of application, but no evidence of upward
movement was noted.
Trials to evaluate the efficacy of glass-encapsulated M:[TC in Douglas-fir
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and southern pine poles are now in their second year. The results continue to
indicate the MITC levels are higher in Douglas-fir poles. The reasons for this
descrepancy are unclear, but may reflect an increased MITC loss from the more
permeable southern pine poles. Controlled studies of MITC release rates from the
glass vials show that the tubes retain chemical for 1 to 2 years under normal
conditions. Faster losses occur under more tropical conditions, while little
loss occurs in cold conditions.
Evaluations of additives to enhance Basamid decomposition in Douglas-fir
pole sections indicate that the presence of copper sulfate and pH 12 buffer
markedly improve the rate of decomposition to MuG one year after chemical
application. More controlled laboratory studies are underway to better
understand this effect.
The trials to evaluate the effects of voids on fumigant movement continue
to indicate that the void has little effect on chemical concentration. These
results indicate that fumigant treatment of poles with voids is feasible provided
the wood retains adequate strength.
Laboratory trials to develop diffusion coefficients for chloropicri.n
movement through Douglas-fir heartwood have been developed. As expected,
chioropicrin movement was most rapid longitudinally and at the fiber saturation
point. Drier wood retained more chemical, slowing diffusion. The diffusion
coefficients will be employed in the fumigant model currently being evaluated on
MITC. The model indicates that MITC movement was greatest at moderate moisture
levels (22 or 44 %), while higher or lower moisture regimes limited chemical
movement. The results obtained using the model will be confirmed through
laboratory trials and by comparison with the results of chemical analyses
performed on the glass-encapsulated MITC trials.
The trials to identify potential replacements for pentachlorophenol for
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remedial treatments are continuing. A number of chemicals have been identified
for both the protection of field drilled bolt holes and the spray treatment of
western redcedar sapwood. Spray treatments of the most promising chemicals will
be applied to western redcedar poles in service.
The identification of small scale tests for detecting decay or estimating
residual strength are continuing. We also continue to evaluate the effectiveness
of various pretreatments for improving treatment and performance of poles. The
effects of through boring and radial drilling patterns on treatment were
evaluated on a glue-laminated Douglas-fir pole. While some differences were
noted in the patterns, the pole was too well-treated to permit effective
separation of the various patterns.
The air-seasoning studies are now completed. Evaluation of the final pahse
of this study showed that decay fungi began to colonize the pole sections after
only 3 months of air-seasoning. Examination of weather data failed to provide
a conclusive relationship between climate and colonization, possibly due to the
array of variables to which the seasoning wood is subjected. The test suggests
that most poles are adequately dried within three months of air-seasoning so that
short air-seasoning exposures could be feasible. Sterilization at some point
during the treatment cycle should still be considered as an integral part in the
proper treatment of poles.
Field trials to evaluate the performance of modified groundline wrap
systems are continuing at both the Corvallis site and on a test line near
Modesto, CA. The results at the Corvallis site indicate the copper naphthenate,
boron, and fluoride are all moving well into the wood eighteen months after
application. More controlled laboratory trials on one formulation suggest that
the water soluble copper naphthenate can migrate for some distance into the wood
within six months after application. As expected, wet wood permits more
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substantial diffusion.
Evaluation of copper naphthenate treated western redcedar stakes in a
fungus cellar suggests that the specified treatment levels are providing adequate
protection, although some decay is occurring. Stakes which were obtained from
weathered sapwood appear to be failing more rapidly those cut from freshly sawn
lumber, possibly because the former stakes have a more open structure which
permits leaching losses and subsequent fungal colonization.