Index Catalog // ScholarsArchive@OSU

Excited state molecular structural evolution and chemical reactivity studied by femtosecond stimulated Raman spectroscopy

Creator:: Han, Fangyuan
Abstract:: In this dissertation, my research work on excited state dynamics of small organic molecules in solutions is presented. Using femtosecond stimulated Raman spectroscopy (FSRS) as the main experimental tool, the excited state hydrogen-bonding dynamics (ESHBD) of Coumarin 102, a common laser dye molecule, in ethanol solution is examined with <150...
Resource Type:: Dissertation
Full Text:: common laser dye molecule, in ethanol solution is examined with <150 fs time resolution. The dynamics

Bridging the Gap Between Equilibrium Properties and Ultrafast Dynamics with Time-Resolved Spectroscopy of Functional Systems

Creator:: Krueger, Taylor D.
Abstract:: Ultrafast spectroscopy has recently gained momentum as a powerful, noninvasive characterization toolset capable of studying a diverse array of samples with applications in chemistry, physics, biology, engineering, and more. Two popular ultrafast spectroscopic techniques include femtosecond transient absorption (fs-TA) and femtosecond stimulated Raman spectroscopy (FSRS). The latter of these techniques...
Resource Type:: Dissertation
Full Text:: transient absorption (fs-TA) and femtosecond stimulated Raman spectroscopy (FSRS). The latter of these

Dynamics and Design of Green Fluorescent Protein-Inspired Superphotoacids and Red-Emitting Fluorophores with Transient Absorption and Femtosecond Stimulated Raman Spectroscopy

Creator:: Chen, Cheng
Abstract:: In the past decades, femtosecond stimulated Raman spectroscopy (FSRS) has been gaining tremendous popularity in fundamental sciences stemming from chemistry to biology. It is capable of capturing both equilibrium and non-equilibrium structural information across a broad range of timescales with simultaneously high temporal and spectral resolutions. Femtosecond transient absorption spectroscopy...
Resource Type:: Dissertation
Full Text:: absorption spectroscopy (fs-TA) acts as a powerful partner technique that complements the dynamics analysis

Probing structural evolution along multidimensional reaction coordinates with femtosecond stimulated Raman spectroscopy

Creator:: Frontiera, Renee R., Fang, Chong, Dasgupta, Jyotishman, and Mathies, Richard A.
Abstract:: Mapping out multidimensional potential energy surfaces has been a goal of physical chemistry for decades in the quest to both predict and control chemical reactivity. Recently a new spectroscopic approach called Femtosecond Stimulated Raman Spectroscopy or FSRS was introduced that can structurally interrogate multiple dimensions of a reactive potential energy...
Resource Type:: Article
Full Text:: (~50 fs) and spectral (~8 cm-1) resolution, thus enabling one to follow reactive structural

Capturing Molecular Movies of Organic and Organometallic Systems in Solution by Ultrafast Spectroscopy

Creator:: Boulanger, Sean A.
Abstract:: Ultrafast spectroscopy can exploit the structure-function relationship of chemical- and biological-based systems. More specifically, femtosecond stimulated Raman spectroscopy (FSRS) provides ground- and excited-state vibrational information with simultaneously high spectral (spatial) and temporal resolutions. The electronic counterpart, femtosecond transient absorption (fs-TA), complements FSRS data analysis as part of a comprehensive approach...
Resource Type:: Dissertation
Full Text:: (spatial) and temporal resolutions. The electronic counterpart, femtosecond transient absorption (fs-TA

Revealing Ultrafast Dynamics and Functional Basis of Potential Biomedical Tools from Calcium Sensing to Optogenetics

Creator:: Tachibana, Sean R.
Abstract:: Photoactivated biomedical tools like fluorescent biosensors and optogenetic proteins have increased in popularity due to the precision targeting and activation used for in vivo applications. In nature, the initially discovered parent proteins exhibit properties such as fluorescence quantum yield (FQY), fluorescence color, and photoswitching dynamics that are unfavorable in mammalian...
Resource Type:: Dissertation
Full Text:: such as femtosecond transient absorption (fs-TA) and femtosecond stimulated Raman

Tracking Excited State Proton Transfer and Inhibition with Ultrafast Raman and Transient Absorption Spectroscopy

Creator:: Oscar, Breland G.
Abstract:: In this dissertation, excited state proton transfer (ESPT) and its inhibition in solution and protein environments are revealed using both femtosecond transient absorption (fs-TA) spectroscopy and femtosecond stimulated Raman spectroscopy (FSRS). Using a tunable Raman pump to enhance transient vibrational features of the photoacidic chromophore HPTS in methanol and methanol...
Resource Type:: Dissertation
Full Text:: in solution and protein environments are revealed using both femtosecond transient absorption (fs

Tracking Photoinduced Primary Events with Femtosecond Stimulated Raman Spectroscopy and Calculations

Creator:: Wang, Yanli
Abstract:: Femtosecond stimulated Raman spectroscopy (FSRS) is a powerful ultrafast technique which can track photoinduced excited state structural events on femtosecond (fs) to picosecond (ps) timescales. In addition to high temporal and spectral resolutions, FSRS provides a broad spectral window from ca. 100—2000 cm-1 for detection, enabling the direct mapping of...
Resource Type:: Dissertation
Full Text:: state structural events on femtosecond (fs) to picosecond (ps) timescales. In addition to high

Natural and semi-synthetic compounds with biocidal activity against arthropods of public health importance

Creator:: Khasawneh, Mohammad A.
Abstract:: This study identified new compounds with pest control activities. The two sources of candidates that were followed here were the main heartwood extract of Alaska Yellow Cedar (AYC) constituents and several semi-synthetic counterparts. Five compounds were isolated and identified for the first time in AYC heartwood in this research: two...
Resource Type:: Dissertation
Full Text:: -enecarboxylic acid (63). The two sesquiterpenes were (5 S,7R, 1 OR, 11 R)-eudesm-4(l 4)-ene- 11,1 2-diol (46

Determination of fluorochemicals in waste-dominated aqueous systems

Creator:: Huset, Carin A.
Abstract:: While fluorochemicals have been detected all over the world and in wastewater treatment plants, the effect of wastewater effluent on the receiving waters has not been evaluated. In the first study, the mass flow of fluorochemicals emanating from wastewater treatment plants along the Glatt River in Switzerland was evaluated. The...
Resource Type:: Dissertation
Full Text:: dominant species observed in landfill leachates. PFBA concentrations ranged from 63 – 1800 ng/L and PFOA

ScholarsArchive@OSU

Excited state molecular structural evolution and chemical reactivity studied by femtosecond stimulated Raman spectroscopy

Bridging the Gap Between Equilibrium Properties and Ultrafast Dynamics with Time-Resolved Spectroscopy of Functional Systems

Dynamics and Design of Green Fluorescent Protein-Inspired Superphotoacids and Red-Emitting Fluorophores with Transient Absorption and Femtosecond Stimulated Raman Spectroscopy

Probing structural evolution along multidimensional reaction coordinates with femtosecond stimulated Raman spectroscopy

Capturing Molecular Movies of Organic and Organometallic Systems in Solution by Ultrafast Spectroscopy

Revealing Ultrafast Dynamics and Functional Basis of Potential Biomedical Tools from Calcium Sensing to Optogenetics

Tracking Excited State Proton Transfer and Inhibition with Ultrafast Raman and Transient Absorption Spectroscopy

Tracking Photoinduced Primary Events with Femtosecond Stimulated Raman Spectroscopy and Calculations

Natural and semi-synthetic compounds with biocidal activity against arthropods of public health importance

Determination of fluorochemicals in waste-dominated aqueous systems

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