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Filtering by: Creator Hughes, Glen Remove constraint Creator: Hughes, Glen Academic Affiliation Chemistry Remove constraint Academic Affiliation: Chemistry

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Hydrogen abstraction from substituted t-butylbenzenes

Creator:

Harvey, Robert Louis

Abstract:

A study of the relative rates of the alkyl hydrogen abstraction from a series of meta and para substituted t-butylbenzenes by the chlorine atom at 70°C has been carried out. Application of the Hammett equation yielded a ρ value of -0.44 for the para compounds. Possible explanations for the non-linearity...

Resource Type:

Masters Thesis

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has time to occur. Backhurst, Hughes, and Ingold (3) have also shown that migration occurs in the
Steric effects in free-radical hydrogen atom abstraction reactions

Creator:

Totherow, William D.

Abstract:

A study of the relative rates of benzylic hydrogen abstractions from a series of meta and para substituted neopentylbenzenes by the bromine radical and trichloromethyl radical at 70°C has been carried out. Application of the Hammett equation yields p values of -0.75 for the bromine atom and -0.94 for the...

Resource Type:

Masters Thesis
Quantitative determination of emerging contaminants, solvent stabilizers and fullerene nanomaterials, in biological and environmental systems

Creator:

Isaacson, Carl W.

Abstract:

To determine the impact of emerging environmental contaminants on human and environmental health, quantitative analytical methods are required. Analysis of emerging contaminants is hampered by their widely varying physical-chemical properties. Therefore quantitative analytical methods must be developed to determine the behavior of emerging contaminants in environmental systems. A quantitative analytical...

Resource Type:

Dissertation

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possible without the excellent technical expertise provided by Glen Wilson, Joe Magner, Jeff Morre, Brian
The kinetic and radiolytic aspects of control of the redox speciation of neptunium in solutions of nitric acid

Creator:

Precek, Martin

Abstract:

Neptunium, with its rich redox chemistry, has a special position in the chemistry of actinides. With a decades-long history of development of aqueous separation methods for used nuclear fuel (UNF), management of neptunium remains an unresolved issue because of its not clearly defined redox speciation. Neptunium is present in two,...

Resource Type:

Dissertation

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Academic Affiliation

Chemistry[remove]4

Advisor

Gleicher, Gerald Jay2
Field, Jennifer A.1
Paulenova, Alena1

Commencement Year

Commencement Year range begin – Commencement Year range end

Current results range from 1969 to 2013

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Committee Member

Barofsky, Douglas1
Dolan, Mark1
Ingle, James1
Ingle, James D.1
Kolluri, Siva1
more Committee Members »

Creator

Harvey, Robert Louis1
Isaacson, Carl W.1
Precek, Martin1
Totherow, William D.1

Date

Date range begin – Date range end

Current results range from 1968 to 2012

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Decade

2010-20191
2000-20091
1960-19692

Degree Field

Chemistry4

Degree Level

Doctoral2
Master's2

Degree Name

Doctor of Philosophy (Ph.D.)2
Master of Science (M.S.)2

File Format

application/pdf1

Language

English [eng]4

License

All rights reserved2

Non-Academic Affiliation

Oregon State University. Graduate School4

Peer Reviewed

No4

Resource Type

Dissertation2
Masters Thesis2

Rights Statement

Copyright Not Evaluated2
In Copyright2

Subject

Hydrogen2
Dioxane -- Toxicity testing1
Emerging contaminants in water -- Toxicity testing1
Fullerenes -- Toxicity testing1
Neptunium -- Speciation1
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