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The chemistry of acetohydroxamic acid related to nuclear fuel reprocessing

Creator:: Matteson, Brent Searle
Abstract:: Used Nuclear Fuel (UNF) contains transuranic (TRU) elements and numerous fission products as a result of the uranium fission process and neutron activation that occur in commercial light water power reactors. Recent environmental and nuclear proliferation concerns have spawned the development of advanced reprocessing techniques to close the nuclear fuel...
Resource Type:: Dissertation
Full Text:: presented on May 27, 2010. Title: The Chemistry of Acetohydroxamic Acid Related to Nuclear Fuel

High-resolution infrared studies of the ν10, ν11, ν14, and ν18 levels of [1.1.1]propellane

Creator:: Kirkpatrick, Robynne, Masiello, Tony, Martin, Matthew, Nibler, Joseph W., Maki, Arthur, Weber, Alfons, and Blake, Thomas A.
Abstract:: This paper is a continuation of earlier work in which the high resolution infrared spectrum of [1.1.1]propellane was measured and its k and l structure resolved for the first time. Here we present results from an analysis of more than 16,000 transitions involving three fundamental bands v₁₀ (E' - A'₁),...
Resource Type:: Article
Full Text:: studies of the Î½10, Î½11, Î½14, and Î½18 levels of [1.1.1]propellane Journal of Molecular Spectroscopy

Coriolis analysis of several high-resolution infrared bands of bicyclo[111]pentane-d₀ and -d₁

Creator:: Perry, A., Martin, M. A., Nibler, J. W., Maki, A., Weber, A., and Blake, T. A.
Abstract:: High-resolution infrared absorption spectra have been analyzed for two bicyclo[111]pentane isotopologues, C₅H₈ (-d₀) and C₅H₇D (-d₁), where in the latter the D-atom replaces a hydrogen on the C₃ symmetry axis such that the molecular symmetry is reduced from D₃ₕ to C₃ᵥ. Two (a"₂) parallel bands, v₁₇ and v₁₈, of bicyclopentane-d₀...
Resource Type:: Article
Full Text:: high-resolution infrared bands of bicyclo[111]pentane-d0 and -d1 Journal of Molecular Spectroscopy

Structural and magnetic investigation of Fe3+ and Mg2+ substitution into the trigonal bipyramidal site of InGaCuO4

Creator:: Grajczyk, Rosa, Berthelot, Romain, Muir, Sean, Sleight, A. W., and Subramanian, M. A.
Abstract:: The solid solutions of InGa₁₋ₓFeₓCuO₄, InFeCu₁₋ₓMgₓO₄, and InGa₁₋ₓFeₓCu₁₋ₓMgₓO₄ were synthesized and characterized through the use of X – ray and neutron diffraction, and DC – magnetism measurements. All compositions of InGa₁₋ₓFeₓCuO₄ are single phase and crystallize in the R3m space group, but a transformation to the spinel InFeMgO₄ structure was...
Resource Type:: Article
Full Text:: . Mohri, Journal of Solid State Chemistry 60 (1985) 382–384. [2] N. Kimizuka, T. Mohri, Journal of

Probing structural evolution along multidimensional reaction coordinates with femtosecond stimulated Raman spectroscopy

Creator:: Frontiera, Renee R., Fang, Chong, Dasgupta, Jyotishman, and Mathies, Richard A.
Abstract:: Mapping out multidimensional potential energy surfaces has been a goal of physical chemistry for decades in the quest to both predict and control chemical reactivity. Recently a new spectroscopic approach called Femtosecond Stimulated Raman Spectroscopy or FSRS was introduced that can structurally interrogate multiple dimensions of a reactive potential energy...
Resource Type:: Article
Full Text:: , Chong Fang2, Jyotishman Dasgupta3 and Richard A. Mathies4* 1Department of Chemistry, Northwestern

Total synthesis of the marine toxin phorboxazole A using palladium(II)-mediated intramolecular alkoxycarbonylation for tetrahydropyran synthesis

Creator:: Kuntiyong, Punlop, Lee, Tae Hee, Kranemann, Christian L., and White, James D.
Abstract:: The potent antitumor agent phorboxazole A was synthesized from six subunits comprising C1-C2 (115), C3-C8 (98), C9-C19 (74), C20-C32 (52), C33-C41 (84) and C42-C46 (85). Tetrahydropyrans B and C containing cis-2,6-disubstitution were fabricated via palladium(II)-mediated intramolecular alkoxycarbonylation which, in the case of tetrahydropyran C, was carried out with catalytic palladium(II)...
Resource Type:: Article
Full Text:: journal is © The Royal Society of Chemistry [year] Org. Biomol. Chem., 20xx, xx, 00–00 | 1 Total

A comprehensive comparison of transition-metal and actinyl polyoxometalates

Creator:: Nyman, May and Burns, Peter C.
Abstract:: While the d⁰ transition-metal POMs of Group V (V⁵⁺, Nb⁵⁺, Ta⁵⁺) and Group VI (Mo⁶⁺, W⁶⁺) have been known for more than a century, the actinyl peroxide POMs, specifically those built of uranyl triperoxide or uranyl dihydroxidediperoxide polyhedra, were only realized within the last decade. While virtually every metal on...
Resource Type:: Article
Full Text:: –7367 This journal is c The Royal Society of Chemistry 2012 Cite this: Chem. Soc. Rev., 2012, 41, 7354

The nuclear reduction of certain pyrimidines with palladized charcoal

Creator:: Aft, Harvey
Resource Type:: Dissertation
Full Text:: to 7 3, 4, 5, 6-tetrahydropyrimiaine in the presence of ada and stated that nuclear

Protein Adducts of Aldehydic Lipid Peroxidation Products: Identification and Characterization of Protein Adducts Using an Aldehyde/Keto Reactive Probe in Combination with Mass Spectrometry

Creator:: Maier, Claudia S., Chavez, Juan, Wang, Jing, and Wu, Jianyong
Abstract:: This chapter describes a mass spectrometry-based strategy that facilitates the unambiguous identification and characterization of proteins modified by lipid peroxidation-derived 2-alkenals. The approach employs a biotinylated hydroxyl amine derivative as an aldehyde/keto reactive probe in conjunction with selective enrichment and tandem mass spectrometric analysis. Methodological details are given for model...
Resource Type:: Part of Book
Full Text:: catch and photorelease of protein-HNE adducts employing ex vivo click chemistry (Kim et al., 2009

Highly Regioselective Nitrile Oxide Dipolar Cycloadditions with ortho-Nitrophenyl Alkynes

Creator:: McIntosh, Melissa L., Naffziger, Michael R., Ashburn, Bradley O., Zakharov, Lev N., and Carter, Rich G.
Abstract:: The dipolar cylcoadditions of ortho-nitrophenyl alkynes with aryl nitrile oxides has been demonstrated. A range of substituents are tolerated on the alkyne. These reactions proceed with excellent levels of regioselectivity. Subsequent functionalization of the isoxazole scaffold has been demonstrated.
Resource Type:: Article
Full Text:: Society of Chemistry [year] Journal Name, [year], [vol], 00–00 | 9 and concentrated in vacuo to give

ScholarsArchive@OSU

The chemistry of acetohydroxamic acid related to nuclear fuel reprocessing

High-resolution infrared studies of the ν10, ν11, ν14, and ν18 levels of [1.1.1]propellane

Coriolis analysis of several high-resolution infrared bands of bicyclo[111]pentane-d₀ and -d₁

Structural and magnetic investigation of Fe3+ and Mg2+ substitution into the trigonal bipyramidal site of InGaCuO4

Probing structural evolution along multidimensional reaction coordinates with femtosecond stimulated Raman spectroscopy

Total synthesis of the marine toxin phorboxazole A using palladium(II)-mediated intramolecular alkoxycarbonylation for tetrahydropyran synthesis

A comprehensive comparison of transition-metal and actinyl polyoxometalates

The nuclear reduction of certain pyrimidines with palladized charcoal

Protein Adducts of Aldehydic Lipid Peroxidation Products: Identification and Characterization of Protein Adducts Using an Aldehyde/Keto Reactive Probe in Combination with Mass Spectrometry

Highly Regioselective Nitrile Oxide Dipolar Cycloadditions with ortho-Nitrophenyl Alkynes

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