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The oxidation of trimethylamine by copper (II) chloride

Creator:: Lane, Thomas Alfred
Abstract:: This research was on the irreversible oxidation of trimethylamine by copper(II) chloride, which takes place at temperatures of about 75° and higher. The coordination of trimethylamine by copper(II) chloride, which is a preliminary reaction to the oxidation, was studied at 0°. The coordination of trimethylamine by the potential reduction product,...
Resource Type:: Masters Thesis
Full Text:: such as those described by Sanderson33 and by Shriver, 35 with a pressure of < 105 torr, was used in

Evidence for a stepwise mechanism in the cycloreversion of rhenium diolates

Creator:: Ness, Stephanie L.
Resource Type:: Masters Thesis

Designing chiral rhenium (VII) trioxo complexes

Creator:: Juniku, Rajan B.
Abstract:: The epoxide deoxygenation reaction is formally the reverse of theepoxidation reaction. Compared to epoxidation, which has reached its fullmaturity, epoxide deoxygenation has not been as intensively developed.Among the few deoxygenation reagents, a handful are catalytic in a metalcomplex, show high stereospecificity and operate under mild conditions. Acommon feature of all...
Resource Type:: Masters Thesis

Studies on the synthesis and characterization of polymer-containing nanocomposite materials

Creator:: Oriakhi, Christopher O., 1960-
Resource Type:: Dissertation

Synthesis and study of transparent p- and n-type semiconductors and luminescent materials

Creator:: Park, Cheol-Hee
Abstract:: New transparent p- and n-type semiconductors and luminescent materials have been prepared and characterized. Synthesis, structures, optical and electrical properties of new chalcogenide fluoride p-type transparent semiconductors MCuQF (M=Ba, Sr; Q=S, Se, Te) are described. Band-gap tuning and improvement in conductivity through p-type doping are demonstrated in the family. The...
Resource Type:: Dissertation

Direct atom transfer vs. ring expansion in reaction of rhenium oxo complexes with cyclooctene epoxides and episulfides

Creator:: Khownium, Kriangsak
Abstract:: The rhenium (V) complex Tp'ReO₂ (Tp' = hydrido-tris-(3,5- dimethylpyrazolyl)borate), generated in situ from PPh₃ reduction of Tp'Re0₃, reacts with small ring heterocycles such as epoxides and episulf ides. The strained trans-cyclooctene ring provides an unusual thermodynamic bias against direct atom transfer, but trans-cyclooctene oxide still produces substantial amounts of trans-cyclooctene....
Resource Type:: Masters Thesis

The oxidation of triethylamine by thallium(III) chloride

Creator:: Arneson, Robert Lawrence
Abstract:: The oxidation of triethylamine by the two electron oxidant thallium(III) chloride was studied and the results compared to those when triethylamine is oxidized by copper(II) halides. This study requires anhydrous conditions since in an aqueous system thallium(III) chloride is extensively hydrolyzed and triethylamine causes precipitation of thallium(III) oxide. Most of...
Resource Type:: Masters Thesis

Synthesis, characterization, and reactivity of rhenium dithiodiolate and monothiodiolate complexes

Creator:: Chuawong, Pitak
Abstract:: The rhenium dithiodiolate, Hydrido-tris-(3 ,5-dimethyl- 1 -pyrazol yl) borato(ethane- 1 ,2-dithiodiolato)(oxo)rheni um(V), and Hydrido-tris-(3 ,5-dimethyl- 1 -pyrazolyl)borato(phenylethanedithiodiolato)(oxo)rhenium(V), were synthesized by reductive cyclocondensation of alkane-1,2-dithiols with Tp'Re0₃ in a one pot fashion. The rhemium monothiodiolate, Hydrido-tris-(3 ,5-dimethyl- 1 -pyrazolyl) borato(ethane- 1 ,2-monothiodiolato)(oxo)rhenium(V), and Hydrido-tris-(3 ,5- dimethyl- 1 -pyrazolyl)borato(propanemonothiodiolato)(oxo)rhenium(V), were also synthesized...
Resource Type:: Masters Thesis

Gaseous electron-diffraction investigations : I. Molecular structures of Os(CO)₅, Ru(CO)₅, and CrOF₄. II. Molecular structures and anti-gauche compositions of BrCH₂,CH₂,F, BrCH₂CH₂C1, C1CH₂CH₂F,C1₂CHCHC1₂, and FCH₂CH₂OH

Creator:: Huang, Jinfan
Resource Type:: Dissertation
Full Text:: Chemical bond", 3rd ed.; Cornell University Press: Ithaca, NY, 1960;. (2) Bethe, H. Ann. Physik, 1929, [5

Applications of redox indicators for evaluating redox conditions in environmental samples

Creator:: Jones, Brian Dion
Resource Type:: Dissertation

ScholarsArchive@OSU

The oxidation of trimethylamine by copper (II) chloride

Evidence for a stepwise mechanism in the cycloreversion of rhenium diolates

Designing chiral rhenium (VII) trioxo complexes

Studies on the synthesis and characterization of polymer-containing nanocomposite materials

Synthesis and study of transparent p- and n-type semiconductors and luminescent materials

Direct atom transfer vs. ring expansion in reaction of rhenium oxo complexes with cyclooctene epoxides and episulfides

The oxidation of triethylamine by thallium(III) chloride

Synthesis, characterization, and reactivity of rhenium dithiodiolate and monothiodiolate complexes

Gaseous electron-diffraction investigations : I. Molecular structures of Os(CO)₅, Ru(CO)₅, and CrOF₄. II. Molecular structures and anti-gauche compositions of BrCH₂,CH₂,F, BrCH₂CH₂C1, C1CH₂CH₂F,C1₂CHCHC1₂, and FCH₂CH₂OH

Applications of redox indicators for evaluating redox conditions in environmental samples

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