Index Catalog // ScholarsArchive@OSU

Himeradine A : synthetic efforts towards himeradine A and related natural products, a Michael reaction focused approach

Creator:: Collett, Nathan D.
Abstract:: Lycopodium alkaloids have generated enormous amounts of interest from the scientific community, both as synthetic targets and for their medicinal properties. Herein is described work towards a unifying approach to large segments of the Lycopodium family. An organocatalyzed intramolecular heteroatom Michael reaction method, for the construction of piperidine and piperizine...
Resource Type:: Dissertation
Full Text:: Nathan D. Collett for the degree of Doctor of Philosophy in Chemistry presented on September 26, 2013

Theoretical and experimental factors affecting the accuracy and precision of atomic absorption measurements

Creator:: Bower, Nathan Wayne
Abstract:: A procedure for evaluating the precision of atomic absorption measurements is presented and applied to 21 elements under varying instrumental conditions. The experimental relative standard deviations (RSD's) in absorbance obtained from repetitive measurements made with a high resolution voltmeter and on-line computer, are compared to those predicted by a recently...
Resource Type:: Dissertation
Full Text:: and precision of atomic absorption measurements AM ABSTRACT OF THE THESIS OF Nathan Wayne Bower for

From electrophoresis to dielectrophoresis: designing, fabricating, and evaluating an electroformed ratchet type microfluidic dielectrophoresis device

Creator:: Gonzalez, Carlos F.
Abstract:: Dielectrophoresis (DEP) is a separation method in which a non-uniform electric field is used to induce a dipole moment in a suspended particle. If the polarization of the particle is greater than that of the suspending medium, the particle will move towards the region of higher field strength (positive DEP);...
Resource Type:: Dissertation
Full Text:: to my committee members: Dr. Nathan Ballou, Dr. James Ingle, Dr. Brian Paul, Dr. William Warnes

Synthesis of α-Ketoester- and α-Hydroxyester-Substituted Isoindazoles via the Thermodynamic Coarctate Cyclization of Ester-Terminated Azo-Ene-Yne Systems

Creator:: McClintock, Sean P., Forster, Nathan, Herges, Rainer, and Haley, Michael M.
Abstract:: The synthesis of isoindazoles bearing α-ketoester and α-hydroxyester groups via the coarctate cyclization of ester terminated azo-ene-yne precursors is described. Whereas previous studies on isoindazole formation have shown the reaction to proceed through a kinetic coarctate pathway, functionalization of the terminal acetylene with a methyl ester sufficiently stabilizes the carbene...
Resource Type:: Article
Full Text:: Cyclization of Ester-Terminated Azo-Ene-Yne Systems Sean P. McClintock†, Nathan Forster†, Rainer Herges

Hydrogen/deuterium exchange mass spectrometry as a technology platform for studying conformational dynamics in large protein complexes

Creator:: Nirudodhi, Sasidhar N.
Abstract:: Proteins are essential to all biological systems. Proteins participate in numerous cellular processes by interacting with other proteins, other metabolites and membranes in a dynamic environment. Studying the structural and conformational properties of proteins in the solution phase is necessary to understand their protein folding and interaction dynamics. This research...
Resource Type:: Dissertation

Chemical composition studies of Oregon and Washington coastal basalts

Creator:: Hill, Dale Wayne
Abstract:: Basalts of both Eocene and Miocene age from several groups along the Oregon and Washington coasts have been analyzed for some major, minor, and trace elements using instrumental neutron activation analysis (INAA). The rare earth element (REE) patterns observed in these samples are used for comparisons within the groups studied...
Resource Type:: Masters Thesis
Full Text:: would like to thank Dr. J. C. Laul of the Oregon State University Radiation Center for his valuable

Active site studies and design of ligands for affinity column separation of 2,5-dihydroxyacetanilide epoxidase (DHAE) I and II

Creator:: Allen, Scott E.
Abstract:: A series of compounds, 7-8 and 20-25, were tested as competitive inhibitors of 2,5-dihydroxyacetanilide epoxidase I (DHAE I) and DHAE II. A Hammett plot was constructed for each enzyme to determine the effect of electron density on inhibition. DHAE I gave a linear, highly correlated plot (r²=0.91) that signifies the...
Resource Type:: Dissertation
Full Text:: inhibitors of CEase varied fragment enzyme AG0 (kJ/mol) MGf (J/mol*A3) N-alkyl chain rat CEase 14 ± 2

Enzymatic studies of the prenatal chick, with special reference to the multibple forms of liver soluble NADP-linked isocitric dehydrogenase

Creator:: Cheung, Geoffrey Peter
Abstract:: Levels of activity of glucose-6-phosphate- , 6-phosphogluconate- , and isocitric- dehydrogenase were measured in the soluble and particulate fractions of heart, brain and liver at several ages throughout the development of the chick embryo. Compared to isocitric dehydrogenase, levels of glucosesphosphate- , and 6-phosphogluconate- dehydrogenase are generally low. This suggests...
Resource Type:: Dissertation
Full Text:: -S of Glucose-6-ghosghate JDefaydrogenase and 6;J?hoj3j3hj3gluc^nate Dehydrogeriasg 17 The low

The addition of hydrogen bromide to 3-methylcyclohexene

Creator:: Dickison, Robert Hanmore
Resource Type:: Masters Thesis
Full Text:: and encouragement during the course ot this invest!• gation, and to Dr . J. c. :Dec1us tor his help

A unified approach for the total synthesis of C₁₀-functionalyzed Lycopodium alkaloids

Creator:: Saha, Mrinmoy
Abstract:: Lycopodium alkaloids have shown widespread and noteworthy biological activity, consisting of over 250 known natural products. Moreover, their structural complexity and diversity have attracted considerable attention from numerous laboratories including our own. Recently, we have developed a unified approach that would provides access to numerous, previously unprepared C₁₀-functionalized lycopodium alkaloids....
Resource Type:: Dissertation
Full Text:: . Xin Li and Dr. Nathan Collett for their work with me as an alkaloid team. I am really thankful to

ScholarsArchive@OSU

Himeradine A : synthetic efforts towards himeradine A and related natural products, a Michael reaction focused approach

Theoretical and experimental factors affecting the accuracy and precision of atomic absorption measurements

From electrophoresis to dielectrophoresis: designing, fabricating, and evaluating an electroformed ratchet type microfluidic dielectrophoresis device

Synthesis of α-Ketoester- and α-Hydroxyester-Substituted Isoindazoles via the Thermodynamic Coarctate Cyclization of Ester-Terminated Azo-Ene-Yne Systems

Hydrogen/deuterium exchange mass spectrometry as a technology platform for studying conformational dynamics in large protein complexes

Chemical composition studies of Oregon and Washington coastal basalts

Active site studies and design of ligands for affinity column separation of 2,5-dihydroxyacetanilide epoxidase (DHAE) I and II

Enzymatic studies of the prenatal chick, with special reference to the multibple forms of liver soluble NADP-linked isocitric dehydrogenase

The addition of hydrogen bromide to 3-methylcyclohexene

A unified approach for the total synthesis of C₁₀-functionalyzed Lycopodium alkaloids

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