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The interaction of CO, N₂, NO, and O₂ with fourth period metal dihalides

Creator:: Van Leirsburg, Dean Alan
Resource Type:: Dissertation
Full Text:: for the in Chemistry (Major) presented on Ph. D. (Degree) Title: THE INTERACTION OF CO, N2, NO

High-resolution infrared studies of perdeutero-spiropentane, C₅D₈

Creator:: Erickson, Blake Alexander, Ju, X., Nibler, Joesph W., Beaudry, C. M., and Blake, T. A.
Abstract:: Perdeutero-spiropentane (C₅D₈) has been synthesized and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational modes. Gas phase infrared spectra were recorded at a resolution (0.002 cm⁻¹) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis...
Resource Type:: Article
Full Text:: (1966). 16. B.N. Taylor, C.E. Kuyatt, NIST Technical Note No. 1297 (1994), Guidelines for

Development, validation and the application of a congener specific photodegradation model for PBDEs

Creator:: Zeng, Xia
Abstract:: The thermodynamic properties of 39 PBDEs have been calculated using Gaussian 03 on the B3LYP/6-31G(d)//B3LYP/6-31G(d) level. The PBDE congeners' enthalpies of formation increase with increasing number of bromines and show a strong dependence on the bromine substitution pattern. The effects of bromine substitution pattern have been quantitatively studied by GAM...
Resource Type:: Dissertation
Full Text:: photodegradation of PBDEs. Photodegradation experiments were conducted for octa-BDE technical mixture and its

Label-free mass spectrometry-driven methods for elucidating adaptive responses of the hepatic mitochondrial proteome in an alcoholic fatty liver disease model

Creator:: Tzeng, Shin-Cheng
Abstract:: Alcoholic liver disease (ALD) continues to be one of the major public health problems in the United States and worldwide. Complicated by factors including gender, polymorphisms of alcohol-metabolizing enzymes, immunologic factors, exposures to other substances/drugs, hepatic viral infections, nutritional deficiencies, and obesity, ALD is a complex disease that requires a...
Resource Type:: Dissertation
Full Text:: datasets with high technical precision were obtained. By taking advantage of the information-rich

Novel monolithic columns for microscale liquid chromatography and capillary electrochromatography

Creator:: Chirica, Gabriela S.
Abstract:: The challenges prompted by miniaturization of chromatographic systems have led scientists to explore new avenues in the synthesis of stationary phases. Packed capillary columns have found limited application in routine analysis due to a number of technical difficulties, most of which are attributable to the frits. New column designs insure...
Resource Type:: Dissertation
Full Text:: limited application in routine analysis due to a number of technical difficulties, most of which are

Application of laser spectroscopy to structure and dynamics of small molecular systems

Creator:: Bozlee, Brian J.
Abstract:: A variety of laser spectroscopic methods are employed in this thesis research for studies of CF₃NO, an interesting model photodissociative system, and for investigation of low energy rotations and vibrations of small molecules and low molecular weight clusters in free jet expansions. Nonradiative energy decay for electronically excited CF₃NO is...
Resource Type:: Dissertation
Full Text:: transient separation of CF3 and NO photofragments in the matrix cage or appreciable decay through a low

Organic Crystalline Solids : Investigating their Capability, Storage Mechanism and Structural Evolution in Dual-Ion Batteries

Creator:: Rodríguez Pérez, Ismael A.
Abstract:: Widespread installation of renewable energy sources, such as wind and solar, has been delayed by the lack of suitable stationary energy storage solutions. Current large-scale technologies, such as pumped hydro and compressed air, are geographically restricted. This is where electrochemical energy storage - batteries or hybrid capacitors can play a...
Resource Type:: Dissertation
Full Text:: revealed that optimization in DIBs is crucial, where several technical issues have prevented the

Application of the least squares criterion to the determination of molecular compliance constants

Creator:: Ottinger, Robert Stanley
Abstract:: The development of a least squares model for the determination of compliance constants from various combinations of vibration frequency, mean square amplitudes of vibration and centrifugal distortion data is discussed. The resultant model is applied to frequency and mean square amplitude data for NO₂ and N₂O₄ and to frequency and...
Resource Type:: Dissertation
Full Text:: compliance constant treatment of the same problem. It can be assumed with no loss of generality that

Polarization spectroscopy and photodissociation studies of nitroaromatic compounds in the gas phase

Creator:: Abbott, James E.
Abstract:: The central purpose of this dissertation was to explore and expand the use of an uniform electric field for orientation and for subsequent spectroscopic investigation of asymmetric polar molecules in the gas phase. The systems of study were nitrobenzene (NB) and the nitrotoluene (NT) isomers. We were able to quantitatively...
Resource Type:: Dissertation
Full Text:: ........................................................................................... 67 3.9a Spectrum of the NO Fragment Produced by Dissociation of p-NT at 249 nm

Fracture Toughness of Co4Sb12 and In0.1Co4Sb12 Thermoelectric Skutterudites Evaluated by Three Methods

Creator:: Eilertsen, James, Subramanian, M. A., and Kruzic, J. J.
Abstract:: Interstitially filled skutterudites are a promising class of state-of-the-art thermoelectric materials. Although thermoelectrics are exposed to significant thermal stresses, little information is known about the fracture toughness of interstitially doped skutterudites. This work explores the fracture toughness of undoped Co₄Sb₁₂ and indium doped In₀.₁Co₄Sb₁₂ skutterudites using three methods: 1) Vickers...
Resource Type:: Article
Full Text:: using both the COD and SEVNB methods indicating no interstitial embrittlement occurs due to indium

ScholarsArchive@OSU

The interaction of CO, N₂, NO, and O₂ with fourth period metal dihalides

High-resolution infrared studies of perdeutero-spiropentane, C₅D₈

Development, validation and the application of a congener specific photodegradation model for PBDEs

Label-free mass spectrometry-driven methods for elucidating adaptive responses of the hepatic mitochondrial proteome in an alcoholic fatty liver disease model

Novel monolithic columns for microscale liquid chromatography and capillary electrochromatography

Application of laser spectroscopy to structure and dynamics of small molecular systems

Organic Crystalline Solids : Investigating their Capability, Storage Mechanism and Structural Evolution in Dual-Ion Batteries

Application of the least squares criterion to the determination of molecular compliance constants

Polarization spectroscopy and photodissociation studies of nitroaromatic compounds in the gas phase

Fracture Toughness of Co4Sb12 and In0.1Co4Sb12 Thermoelectric Skutterudites Evaluated by Three Methods

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