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Filtering by: Creator Belant, Jerrold L. Remove constraint Creator: Belant, Jerrold L. Advisor Bond, F. Thomas Remove constraint Advisor: Bond, F. Thomas

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  • Formation of alkyl-and dialkylcarbenes. The 3-cyclohexenyl carbinyl carbene system

    Creator:
    Crouse, Dale McClish
    Abstract:
    The 3-cyclohexenyl carbinyl carbene species was formed by the thermal decomposition of the p-toluenesulfonylhydrazone sodium salt and by oxidation of the hydrazone. Several oxidizing agents were studied. The products were investigated under aprotic and protic conditions and at various temperatures. The diazocompound was formed as an intermediate and found to...
    Resource Type:
    Masters Thesis
    Full Text:
    - Cyclohexene -l- Methanol Acetate (XXIII) 99 Azine Decomposition by Ultraviolet Light 99 3

  • The synthesis and chemistry of strained bicyclic systems

    Creator:
    Scerbo, Louis
    Abstract:
    A facile route to bicyclo(2.1.1)hexanes was developed involving the intramolecular photocyclization of 1, 5-hexadien-3-one to bicyclo(2.1.1)hexan-2-one. A study of the chemistry of bicyclo-(2.1.1)hexan-2-one was undertaken. Deuterium exchange and borohydride reduction demonstrated the strain present in the ketone. Further evidence was obtained from the failure to introduce substituents alpha to the...
    Resource Type:
    Dissertation
    Full Text:
    bicyclo(2. 1. 1)hexane derivatives 6 through 11 (115, 116, 117). 6 Cl CO2H 7 cl 10 OH L;k