This study utilizes differential scanning calorimetry (DSC) to characterize the thermodynamics, kinetics and crystallization b processes of a new Pt₅₇.₃Cu₁₄.₆Ni₅.₃P₂₂.₈ bulk metallic glass forming alloy. The heat capacity of the alloy is measured for the crystalline, glassy, and supercooled liquid phases. This data is used to obtain thermodynamic driving forces...
The viscosity of Zr[subscript 41.2]Ti[subscript 13.8]Cu[subscript 12.5]Ni[subscript 10.0]Be[subscript 22.5] (Vit1) has been measured above the liquidus temperature, T[subscript liq]=1026 K, using a high vacuum high temperature rapid annealing furnace equipped with a Couette Concentric Cylinder Rheometer. Steady state measurements have been taken over a temperature range of 1075-1300 K and...
By the investigation of the bulk metallic glass-forming liquids that have very low critical cooling rates, the thermodynamics of metallic glasses can be clarified. For studying thermodynamic properties, such as the specific heat capacity, calorimetry (DSC) is utilized and one of the most used instruments is the differential scanning calorimeter....
Among recently found multi-component Zr-based bulk metallic glasses (BMG), Zr₅₈.₅Cu₁₅.₆Ni₁₂.₈Al₁₀.₃Nb₂.₈ is characterized by its lower critical cooling rate requirement and absence of beryllium as one of the constituent element which makes its handling more convenient. Its large supercooled liquid regions made possible the study of thermodynamics and kinetics of this...
The influence of shear rate and temperature on the viscosity and fragility of the Zr₄₁.₂Ti₁₃.₈Cu₁₂.₅Ni₁₀.₀Be₂₂.₅ (Vit1) metallic glass forming liquid is measured in the liquid and undercooled liquid state between 907 and 1300 K. The results show a complex rheological behavior of Vit1. The viscosity of Vit1 is about three...
This paper documents the investigation into injection molding, or die casting, a bulk metallic glass (BMG). A BMG is an amorphous metal of a thickness greater than 25 μm, according to leading researchers in the field. This critical thickness differentiates a normal metallic glass from a "bulk" metallic glass. The...
A high temperature high vacuum rheometer has been designed, fabricated,
and tested for the study of the steady shear viscosity for multicomponent bulk
metallic glass forming alloys. This rheometer has an operating range up to
1525 K, rotational frequencies of 9.4*10⁻³-3.7*10¹ radians/s, and a
calibrated viscosity range of 9.6*10⁻³ and...