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A study of the chemistry of diisopropyl-, cyclopropylisopropyl-, and dicyclopropylcarbene

Creator:: Wuerch, Stephen E.
Abstract:: The effect of the conjugation with cyclopropyl rings on the activation parameters for the formation of carbenes from the corresponding diazo compounds was investigated using diisopropylcarbene (46), cyclopropyl-isopropylcarbene (47), and dicyclopropylcarbene (48). Each of these three carbenes was generated by the thermolysis of the parent benzenesulfonylhydrazone potassium salts using DMSO...
Resource Type:: Masters Thesis
Full Text:: - sulfonylhydrazones (tosylhydrazones). Bamford and Stevens allowed nineteen different tosylhydrazones to react with

Carbene rearrangements : intramolecular interaction of a triple bond with a carbene center

Creator:: Dan̄ino, José C.
Abstract:: The tosylhydrazones of 2-heptanone, 4,4-dimethy1-2- heptanone, 6-heptyn-2-one and 4,4-dimethy1-6-heptyn-2- one were synthesized and decomposed under a variety of reaction conditions: dry lithium and sodium salt pyrolyses, sodium methoxide thermolyses in diglyme and photolyses of the lithium salt in tetrahydrofuran. The saturated analogues 2-heptanone tosylhydrazone and its 4,4-dimethyl isomer afforded the...
Resource Type:: Dissertation
Full Text:: the fact that the Bamford- Stevens reaction generally furnishes the same carbene by a safer and more

The photochemical transformation of oxime carbamates

Creator:: Ndip, Edmund Moses Nso
Resource Type:: Masters Thesis
Full Text:: Typed by Jo Ann Linch for Edmund Moses Nso Ndip ACKNOWLEDGEMENTS Putting together this first piece

The chemistry of selected carbene and radical ion intermediates

Creator:: Pugh, James K.
Resource Type:: Dissertation
Full Text:: . To generate carbenes in this study the Bamford-Stevens reaction,' which involves the thermal

Mechanistic studies of vinylic carbenes in dimethyl sulfoxide

Creator:: Tafesh, Ahmed Mohammed
Resource Type:: Masters Thesis
Full Text:: on tosylhydrazone as a carbene pre- cursor was published by Bamford and Stevens (9). Their work

Reactive intermediates : I. The mechanisms of photodehalogenation of three tetrachloronaphthalenes : II. Structure and electronic effects in some selected carbenes

Creator:: Clapp, Gary E.
Resource Type:: Dissertation

Divalent carbon intermediates in some bridged polycyclic compounds

Creator:: Hardy, Thomas A.
Resource Type:: Dissertation
Full Text:: . The method of choice was that of the Bamford-Stevens reaction which involves base catalyzed thermal

Vinylcarbene intermediates in some cyclic systems

Creator:: Swenson, Karl Edward
Resource Type:: Dissertation
Full Text:: a 1952 paper by Bamford and Stevens 1 . Tosylhydra- zones can be treated with base and this salt

Reactive intermediates in the tetracyclo-[3.3.0.0² ⁷.0⁴ ⁶] octane, the tetracyclo-[3.3.0.0² ⁴.0³ ⁷] octane, and related ring systems containing the norbornane skeleton

Creator:: Ziebarth, Timothy Dean
Resource Type:: Dissertation
Full Text:: . Previous observations of intermolecular products in the Bamford-Stevens reaction when conducted under

Reactive intermediates in the tricyclo- [3.2.1.0²,⁴] octane ring system

Creator:: Raghavan, Ramaswamy Srinivasa, 1941-
Resource Type:: Dissertation
Full Text:: Mr. Lawrence E. Schick for their kind words of advice and encouragement. Mrs. Mary Ann Blazevich is

ScholarsArchive@OSU

A study of the chemistry of diisopropyl-, cyclopropylisopropyl-, and dicyclopropylcarbene

Carbene rearrangements : intramolecular interaction of a triple bond with a carbene center

The photochemical transformation of oxime carbamates

The chemistry of selected carbene and radical ion intermediates

Mechanistic studies of vinylic carbenes in dimethyl sulfoxide

Reactive intermediates : I. The mechanisms of photodehalogenation of three tetrachloronaphthalenes : II. Structure and electronic effects in some selected carbenes

Divalent carbon intermediates in some bridged polycyclic compounds

Vinylcarbene intermediates in some cyclic systems

Reactive intermediates in the tetracyclo-[3.3.0.0² ⁷.0⁴ ⁶] octane, the tetracyclo-[3.3.0.0² ⁴.0³ ⁷] octane, and related ring systems containing the norbornane skeleton

Reactive intermediates in the tricyclo- [3.2.1.0²,⁴] octane ring system

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