A thermomechanical pulp, a high yield sulfite pulp, and a high yield solvent sulfite pulp from western hemlock [Tsuga heterophylla (Raf.) Sarg.] wood were investigated to determine the amount of carbohydrate material present and to elucidate the structures of the carbohydrates. The effects of the three pulping processes, which were...
The inner bark of Douglas-fir was successively extracted with ethanol-water (4:1 v/v), benzene-ethanol (2:1, v./iv), water, and 0.5% aqueous ammonium oxalate solution. The residue was reacted with acidified sodium chlorite, a commonly used reagent to separate lignin from carbohydrates. In general the reaction dissolves the lignin and leaves the carbohydrates...
Six filtrate samples (liquid state) were obtained from selected stages in a totally-chlorine- free (TCF) bleach pulp mill. The solids were recovered by evaporation on rotary evaporators and by lyophilization with a freeze drier. Chemical contents (inorganic and organic chemicals) of the six filtrates were analyzed quantitatively according to TAPPI...
Dihydroquercetin [(2,3-trans)-3,3',4',5,7-pentahydroxyflavanonol]
was shown to be the precursor to the phenolic
stains that often develop in Douglas-fir [Pseudotsuga
menziesii (Mirb.) Franco] sapwood. Douglas-fir sapwood was
extracted with methanol and the methanol solubles were
fractionated by solvent partition, thin-layer chromatography,
silica-gel column chromatography, and Sephadex gelpermeation
chromatography. Tyrosinase, a commercially
available...
This work is part of a larger project dealing with
nonprocess element (NPE) behaviour in chemical pulping
processes. Nonprocess elements are defined as those
elements which are not essential to the chemical
process, i.e. are neither active pulping chemicals
(e.g., NaOH and Na2S in the kraft process), nor
compounds present...
Chemical stains that develop on commercial woods are
problems of great economic importance. The polyphenol
oxidases catalyze the oxidation of the phenolics that
naturally exist in plants to quinones when the cell structure is disrupted. The quinones produced are further
oxidized and polymerized to melanin, the pigment which is
responsible...