Microbial-induced corrosion of concrete (MICC) is a multi-stage deterioration process caused by microbial activity in wastewater infrastructure. MICC is a worldwide issue due to the reduced service life of the wastewater infrastructure and the economic impact associated with increased maintenance and reconstruction costs. This thesis explores two critical aspect of...
Most of the concrete in the world is produced using hydraulic cement (ordinary portland cement, OPC) and siliceous or alumino-siliceous supplementary cementitious materials (SCM). Due to the shift in focus toward environmental sustainability within the construction industry, alkali-activated cementitious systems (AAC) have gained significant attention to reduce the carbon footprint...
A vital aspect of concrete construction is quality assurance and control (QA/QC). Engineered structures must meet pre-determined and agreed-upon strength and durability requirements. Concrete falls into a specific category of infrastructure material because in most cases, these strength and durability requirements cannot be found until the material has at least...
This thesis builds on a modeling tool that has been developed to link thermodynamic modeling and concrete performance. This tool is intended to predict the performance for modern concrete mixtures made with ordinary portland cement (OPC), conventional and novel supplementary cementitious materials (SCMs), and limestone (Ls). The first part of...
The pozzolanic reactivity test (PRT) is used to quantify the pozzolanic reactivity of supplementary cementitious materials (SCMs). The PRT computes reactivity by measuring heat release (Q) and calcium hydroxide (CH) consumption, as interpreted using thermodynamic modeling. The robustness of PRT is examined by experimentally varying CH-to-SCM ratio, solution-to-solid ratio, sulfate...
Chloride binding in Portland limestone cements (PLC) can be attributed to the chemical reaction between chloride ions and carboaluminate phases to form Friedel’s salt and the physical interaction between chloride ions and calcium-silicate-hydrates (C-S-H). This thesis examines the chloride binding of mortar samples containing varying amounts of limestone, fly ash,...
Low carbon steels (LCS) due to their high strength-to-cost ratio are one of the most ubiquitous materials used for a wide range of applications, including but not limited to automotive, construction, and transportation. However, the low corrosion resistance of LCS in neutral, acidic, or saline environments limits its utilization and...
The aim of this work was to assess the viability of duplex stainless steel 2205 components built via selective laser melting for seawater applications. First, a comprehensive additive manufacturing assessment was done. The duplex stainless steel 2205 components were selectively laser melted from gas atomized powder (D90 <45m) using a...
Thermodynamic modeling of cementitious material is an established tool for predicting the hydrated phase assemblages, pore solution pH, and pore solution composition of mixtures of various chemical compositions and water-to-binder (w/b) ratios. However, traditional thermodynamic techniques have major limitations for modeling mixtures containing supplementary cementitious materials (SCM), and when modeling...
Sustainable wastewater infrastructure systems are vital for civilizations to protect public health. Most of the structural elements of wastewater infrastructure are constructed using concrete owing to its versatility, low cost, and durability. Concrete structures that are exposed to wastewater can experience Microbially Induced Corrosion of Concrete (MICC), which is a...