The rare earth elements (REEs) have been established as powerful tracers for a range of physiochemical processes occurring in the natural environment. They also hold significant economic importance as many technological advancements are reliant upon the REEs for their unique magnetic, luminescent, and electrochemical characteristics. In sedimentary settings, understanding the...
Quantifying the mass transport through marine sediments, and the geochemical response to such flow with numerical models has become a common and powerful approach for geochemical data interpretation. In this dissertation, I developed and applied transport-reaction models to unravel complex and interdependent reactions involving carbon, sulfur and silica transformations in...
The distribution of barite (BaSO₄) in marine sediments has long been studied as a proxy for paleoproductivity. While pure barite is known to be a stable mineral in oxic sediments, it is also known that variations in the Sr/Ba ratio influence its solubility and liability during early diagenesis. To extract...
Nares Strait is one of three main passages of the Canadian Archipelago that
channels freshwater from the Arctic Ocean to the North Atlantic. There are very few
observations regarding the role of this region on the present day Arctic freshwater budget,
and even less regarding the changes in freshwater fluxes...
Large barite (BaSO4) structures mark cold seeps in the southern San Clemente Basin. Barium flux to San Clemente sediments is two to three times greater than fluxes measured in surrounding California Borderland basins. Analyses of sediment trap material, water column samples, sediments and pore water indicate that expected bariumbearing mineral...