The rare earth elements (REEs) have been established as powerful tracers for a range of physiochemical processes occurring in the natural environment. They also hold significant economic importance as many technological advancements are reliant upon the REEs for their unique magnetic, luminescent, and electrochemical characteristics. In sedimentary settings, understanding the...
The Cretaceous was a period of extreme climatic conditions accompanied
by major perturbations in ocean-atmosphere biogeochemical cycles. One of the
most intriguing features is the sporadic interruption of normal marine pelagic
sediment deposition by organic rich sediments deposited during oxygen-deficient
conditions (ocean anoxic events OAEs). A current model for the...
This thesis investigates the behavior of major inorganic nutrients (P, N, Si), trace metals (Mn, Fe), and alkaline-earth metals (Ba) within Tillamook Bay over seasonal cycles and under a range of river discharge conditions from October 1997 through December 1999. Located in the Pacific Northwest region, Tillamook Bay is an...
New chemical synthesis strategies have been investigated for the preparation of acceptor-type graphite intercalation compounds (GIC's) with fluoroanions in order to obtain new materials and to develop a better understanding of the synthetic approaches and properties of the products. New GIC's containing borate chelate anion such as bis(oxalato)borate, CxB[OC(O)C(O)O]₂•δF, are...