Directed energy deposition and laser cladding technologies are suitable advanced manufacturing techniques for applying corrosion-resistant claddings to large carbon steel components. In this work, we clad 309L stainless steel wire onto carbon steel substrates and examine the effects of cladding parameters (laser power and travel speed) on metallurgical bonding, composition,...
This dissertation is concerned with the behavior of sulfur in intermediate-silicic arc magmas associated with subduction at convergent margins. In particular it focusses on oxidized, sulfur-rich magmas, the conditions at which they might reach sulfate saturation, and implications of sulfate saturation. It is divided into an investigation of natural samples...
Phase change memory materials are a set of chalcogenide or pnictogenide materials systems currently being researched for use in optical and resistive based memory systems due to their large change in optoelectronic properties between the amorphous and the crystalline states. For these materials systems to be considered as a suitable...
This dissertation is divided into two major chapters. The first chapter covers the geologyof the Encuentro deposit with emphasis in the intrusion sequence, vein mineral assemblages and distribution, and age of mineralization. The data used for this section includes field mapping, petrography, elemental analysis of biotite, and isotopic geochronology. The...
The corrosion behaviors of carbon and stainless steels were investigated in supercritical CO₂ (sCO₂ ) containing H₂O and O₂ simulating conditions that exist in direct sCO₂ power cycle heat exchangers. Thermodynamic properties of CO₂-H₂O-O₂ systems related to the corrosion phenomena were determined using NIST software. The exposure tests of the...
Solid solutions based on the perovskite ferroelectrics Bi₀.₅Na₀.₅TiO₃ (BNT) and Bi₀.₅K₀.₅TiO₃ (BKT) might someday replace current Pb-based ferroelectric and piezoelectric devices. This is one goal of the Restrictions on Hazardous Substances (RoHS) guidelines seeking to limit Pb in consumer devices. Although the Bi-based ferroelectrics are well suited to the task...
Ceramic injection molding (CIM) is a high volume, near net shaping process used to manufacture ceramic parts with complex features and shapes. In CIM design it is important to understand the molding behavior as a function of powder-polymer (feedstock) composition in order to achieve desired part dimensions and properties, at...
Electric power needs will only grow over the next decades as more humans ascend from poverty into the middle class. Currently, the majority of electric power is generated by burning fossil fuels. To help mitigate the undesirable effects of burning fossil fuels research is being done to increase the efficiency...
Semi-volatile trace metals like Li, Cu, Mo, Sn, In, and Pb have the potential to track mobility of a volatile phase in volcanic systems. In this dissertation four studies are presented that either directly investigate or are motivated by observations of trace metal behavior in volcanic systems. A common tool...
Dielectric ceramics designed for capacitor applications for use in extreme environments, such as high temperatures, high voltages, or high-pressure environments, are in great demand. Existing capacitor technology fails to perform within these extreme conditions or such environments. The development of new dielectric ceramic materials for high temperature capacitor applications is...