Non-dilute salt strength solutions occur in many near surface geologic environments. In order to better understand the occurrence and movement of the water and salt, mathematical models for this non-ideal fluid need to be developed. Initial boundary value problems may then be solved to predict behavior for comparison with observations....
Though many arid and contaminated sites have high salinity, prediction of effects of salinity on water movement in soils has been based on dilute solution approximations. Here a sensitivity analysis compares predicted liquid and vapor pressure in variably saturated porous media found using both the dilute approximations and a more...
Using thermodynamic principles, the general relationship describing the equilibrium vapor content in the gas phase above a saline liquid and across a curved liquid-gas interface is developed. Since high salt concentration also affects the intensive and extensive liquid properties, it is also necessary to account for these effects in liquid...