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Filtragem por: Peerreviewed Label No Creator Choi, Young Bok Degree Field Chemistry Sujeito Organic compounds -- Synthesis

A pyrolysis of cis-1-trimethylsiloxy-1-cyclopropyl-3-cyclononene : the thermal isomerization of 2-phenyl-1-trimethylsiloxy-1-vinylcyclononane

O Criador:

Choi, Young Bok

Abstract:

Part 1 The pyrolysis of cis-1-trimethylsiloxy-1-cyclopr opyl-3-cyclononene in the temperature range 285-350° is described. Instead of siloxy-Cope rearrangement, undesired desiloxylation took place. Part 2 Gas-phase pyrolytic rearrangement of 2-phenyl-1-trimethylsiloxy-1-vinylcyclononane was investigated in a static system in the temperature range 213-330°. It was discovered that three major products resulted: cis- and...

Resource Type:

Masters Thesis

Full Text:

predominate in the product mixture. In any event, there can be no doubt that the homolytic dissociation