A low-voltage plateau at ∼0.3 V is discovered during the deep sodiation of Na₃V₂(PO₄)₃ by combined computational and experimental studies. This new low-voltage plateau doubles the sodiation capacity of Na₃V₂(PO₄)₃, thus turning it into a promising anode for Na-ion batteries.
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batteries
Jian, Z., Sun, Y., & Ji, X. (2015). A new low-voltage plateau of Na₃V₂(PO₄)₃ as an
anode for Na
Na-ion batteries are emerging as one of the most promising energy storage technologies, particularly for grid-level applications. Among anode candidate materials, hard carbon is very attractive due to its high capacity and low cost. However, hard carbon anodes often suffer a low first-cycle Coulombic efficiency and fast capacity fading. In...
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Anode for Na-Ion Batteries via
Graphene Oxide as a Dehydration Agent
Luo, W., Bommier, C., Jian, Z
We, for the first time, demonstrate that orthorhombic V₂O₅ can exhibit superior electrochemical performance in sodium ion batteries when uniformly coated inside nanoporous carbon. The encapsulated V₂O₅ shows a specific capacity as high as 276 mAh/g, while the whole nanocomposite exhibits a capacity of 170 mAh/g. The V₂O₅/C composite was...
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[13] Lu, Y.; Wang, L.; Cheng, J.; Goodenough, J. B. Chem. Commun. 2012, 48, 6544- 6546.
[14] Jian, Z
Sodium-ion batteries are emerging as a highly promising technology for large-scale energy
storage applications. However, it remains a significant challenge to develop an anode with
superior long-term cycling stability and high-rate capability. Here we demonstrate that the
Na⁺ intercalation pseudocapacitance in TiO₂/graphene nanocomposites enables high-rate
capability and long cycle life...
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electrode for
long-life sodium-ion batteries. Nat. Commun 4, 2365 (2013).
9. Jian, Z. L. et al. Superior