By alloying face centered cubic CaSe with orthorhombic SnSe, we created the heterostructural alloy
Sn1-xCaxSe. The phase separated lms created with a high deposition temperature acted as highly crys-
talline SnSe while the low deposition temperature lms acted as a mix of SnSe and CaSe. For the alloyed
lms we...