Index Catalog // ScholarsArchive@OSU

Siloxy-cope rearrangements of the trans-l-vinylcyclotridec-3-en-l-ol system

Creator:: Bolesta, Richard Edward
Abstract:: The thermolysis of trans-1 -trimethylsiloxy- 1-vinylcyclotridec- 3-ene (VI-OTMS) led to the formation of two major products: 4-vinylcyclotridecanone (VII) and cyclopentadec-5-en-l-one (VIII) after hydrolysis. Ketone VII is produced by a concerted [3, 3] sigmatropic shift, while ketone VIII is formed by a [1, 3] sigmatropic shift with a concerted or diradical...
Resource Type:: Masters Thesis
Full Text:: -vinylcyclotridec-3-ene (VI-OTMS). a T°Cb k x 105 (sec-1)c Correlation Coefficient 245.9 0.69 ± .05 0. 997 254.1

Trans-cis isomerization of geraniol and geranyl phosphate by cell-free enzymes from higher plants

Creator:: Shine, Ward Edward
Abstract:: Neryl pyrophosphate, rather than geranyl pyrophosphate, is believed to be the immediate biological precursor of the cyclohexanoid monoterpenes because the cis-2, 3-double bond readily permits cyclization. Biosynthesis of neryl pyrophosphate could occur by either of two principal mechanisms: direct cis condensation of dimethylallyl pyrophosphate with isopentenyl pyrophosphate or trans-cis isomerization...
Resource Type:: Dissertation
Full Text:: phosphate buffer, 10 mM potassium metabisulfite (K 2 S 2 0 5 ), and 0.8% Triton X-100 detergent; the

Siloxy-cope and oxy-cope rearrangements of the cis- and trans-1-vinylcyclodec-3-en-1-ol systems ; Acid-catalyzed rearrangement of cis-bicyclo [6.1.0] nonane-cis- and trans-9-methanols ; An effective two-carbon ring-expansion

Creator:: Billigmeier, James Earl
Resource Type:: Dissertation
Full Text:: Ea = 50. 4 kcal/mol A 1015. 64 k x 105 (sec-1)1D 1. 72 + 0. 03 1.81 + 0. 02 3.85 + 0. 01 32. 1

Geographic and seasonal variation in photosynthetic efficiency and capacity of Rocky Mountain Douglas-fir, Pseudotsuga menziesii var. glauca

Creator:: Pope, Walter William
Abstract:: Net photosynthesis was measured for photosynthetic light efficiency and capacity on two-year-old plants from eight different seed sources in three measurement periods. The measurement periods corresponded to the physiological periods 1) prior to bud swelling, 2) after needle elongation, and 3) predormancy. Measurement period differences in both photosynthetic efficiency and...
Resource Type:: Dissertation
Full Text:: illumination on a horizontal surface within and above the plant stand, respectively; k is the extinction

Finite amplitude deep water waves : a comparison of theoretical and experimental kinematics and dynamics

Creator:: Jensen, Robert E.
Abstract:: Problems associated with quantification of deep water wave kinematics and dynamics are examined. Summaries of Stokes' theory and Dean's stream function theory are reported. A computer algorithm is developed to solve the hydrodynamic characteristics for Stokes' fifth and third order and linear theories. Tests are initiated to verify the results...
Resource Type:: Masters Thesis
Full Text:: EXPERIMENTAL KINEMATICS AND DYNAMICS Redacted for Privacy Abstract approved: Dr. Charles K. Sollitt Problems

Physical structure and reconstitution of chromatin core particles

Creator:: Tatchell, Kelly George
Abstract:: The nucleosome appears to be the basic structural unit of the eukaryotic chromosome. The usual nucleosome preparation, isolated from a micrococcal nuclease digest of nuclei, is heterogenous in DNA length and protein composition with some particles containing spacer DNA and associated protein. This heterogeneity complicated physical and reconstitution studies. As...
Resource Type:: Dissertation
Full Text:: PARTICLES Abstract approved: Redacted for Privacy K. E. Van Ho lde The nucleosome appears to be the basic

Divalent carbon intermediates in some bridged polycyclic compounds

Creator:: Hardy, Thomas A.
Resource Type:: Dissertation
Full Text:: . Peter K. Freaman The generation and attempted generation of carbenes in several alicyclic systems is

Radical anions, radicals and anions : the formation and stereochemistry of alkyl lithium reagents from lithium 4, 4'-Di-tert-butylbiphenyl and alkyl halides

Creator:: Hutchinson, Larry Lee
Resource Type:: Dissertation
Full Text:: approved: ,Redacted for Privacy. Peter K. Freeman The reactions of alkyl halides with metals and radical

Seasonal variations in tidal dynamics, water quality and sediments in the Alsea Estuary

Creator:: McKenzie, David Roller
Abstract:: During 1973 data was collected to analyze the seasonal variations of the tidal dynamics, water quality and sediments of the Alsea Estuary. A summary of historical information with a list of all known alterations to the estuary was made. A complete physical description, including the geographical setting and mixing classification...
Resource Type:: Masters Thesis
Full Text:: ESTUARY Abstract approved: Redacted for Privacy Charles K. Sollitt During 1973 data was collected to

The identification of medicine education learning outcomes for ambulatory, noninstitutionalized older adults

Creator:: Gaeta, Michael J.
Abstract:: The primary purpose of this study was the identification of specific medicine education learning outcomes which are important and appropriate for ambulatory, non-institutionalized older adults. A modification of the Delphi technique was utilized and a panel of 16 national experts was selected on the basis of four criteria to respond...
Resource Type:: Dissertation
Full Text:: Redacted for Privacy Abstract approved: Dr. John\K. El lis The primary purpose of this study was the

ScholarsArchive@OSU

Siloxy-cope rearrangements of the trans-l-vinylcyclotridec-3-en-l-ol system

Trans-cis isomerization of geraniol and geranyl phosphate by cell-free enzymes from higher plants

Siloxy-cope and oxy-cope rearrangements of the cis- and trans-1-vinylcyclodec-3-en-1-ol systems ; Acid-catalyzed rearrangement of cis-bicyclo [6.1.0] nonane-cis- and trans-9-methanols ; An effective two-carbon ring-expansion

Geographic and seasonal variation in photosynthetic efficiency and capacity of Rocky Mountain Douglas-fir, Pseudotsuga menziesii var. glauca

Finite amplitude deep water waves : a comparison of theoretical and experimental kinematics and dynamics

Physical structure and reconstitution of chromatin core particles

Divalent carbon intermediates in some bridged polycyclic compounds

Radical anions, radicals and anions : the formation and stereochemistry of alkyl lithium reagents from lithium 4, 4'-Di-tert-butylbiphenyl and alkyl halides

Seasonal variations in tidal dynamics, water quality and sediments in the Alsea Estuary

The identification of medicine education learning outcomes for ambulatory, noninstitutionalized older adults

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