The tosylhydrazones of 2-heptanone, 4,4-dimethy1-2-
heptanone, 6-heptyn-2-one and 4,4-dimethy1-6-heptyn-2-
one were synthesized and decomposed under a variety of
reaction conditions: dry lithium and sodium salt pyrolyses,
sodium methoxide thermolyses in diglyme and photolyses of
the lithium salt in tetrahydrofuran. The saturated analogues
2-heptanone tosylhydrazone and its 4,4-dimethyl
isomer afforded the...
The photochemistry of some analogs of insect growth regulators
(IGR's) was studied. Methyl geranate, TY, was synthesized and the
mechanisms of its photochemical reaction pathways were studied by a
variety of techniques. Direct irradiation of 71 in ether leads to the
formation of five new products: 98, the product of...
The effect of the conjugation with cyclopropyl rings
on the activation parameters for the formation of
carbenes from the corresponding diazo compounds was
investigated using diisopropylcarbene (46), cyclopropyl-isopropylcarbene
(47), and dicyclopropylcarbene (48).
Each of these three carbenes was generated by the
thermolysis of the parent benzenesulfonylhydrazone
potassium salts using DMSO...
Photolysis of pentachlorobenzene was carried out in the absence
of an electron donor species at 254 nm in cetyltrimethylammonium
bromide surfactant solution. The results are consistent with the
excited triplet undergoing homolytic cleavage of a C-Cl bond in
competition with formation of the excimer, in which the radical anion
undergoes...