In previous work (Blakemore et al. Org. Lett. 2005, 7, 4721; Heterocycles 2006, 70, 609), successful elaborations of the lupine alkaloids (±)-α-isosparteine (dl-2) and (±)-β-isosparteine (dl-3) were realized from a common tetraoxobispidine precursor, 3,7-diallyl -2,4,6,8-tetraoxo-3,7-diazabicyclo[3.3.1]nonane (93). Herein, the tetraoxobispidine approach to lupine alkaloids was extended to a total synthesis of...
The OSU Motor Systems Resource Facility (MSRF), co-directed by the Principal Investigators (PI's, bios included), is an Energy Systems Laboratory with operating capabilities up to 750kV A, testbeds up to 300hp, a 120kVA fully programmable source, and a bi-directional grid interface enabling regeneration back onto the grid. The MSRF was...