A synthetic approach toward the two major fragments of cathedulin K-19,
euonyminol (4) and dimethyl cathate (69), was investigated. Synthesis of
dimethyl cathate was accomplished in 3 steps starting from 73. Efforts directed
towards the synthesis of euonyminol, a highly oxygenated dihydroagarofuran
sesquiterpene, was advanced to a stage in which...
An oscillating plasma glow discharge detector for gas
chromatography is used to obtain fingerprint information
about an analyte by combining both the average cell
current and oscillation frequency signals. Five homologs
each of the n-alkanes, 1-alkenes, 1-alkynes, 2-ketones and
aldehydes are studied. Although triplicate determinations
had some scatter due to...
More that just magnificent views of atoms and
molecules, Scanning Tunneling Microscopy, STM, images have
the potential to answer some fundamental questions relating
to surface molecular dynamics and bonding characteristics of
localized species versus more common analytical tools that
provide average of bulk sample information. A special
feature of the...
The photoelectron spectra of a series of ketone
compounds have been investigated in the gas phase. Core
ionization energies were measured to probe the effects of
molecular size and connectivity number on core ionization
energies.
It was found that core ionization energies roughly
decrease with increasing connectivity number as expected....