The dipolar cylcoadditions of ortho-nitrophenyl alkynes with aryl nitrile oxides has been demonstrated. A range of substituents are tolerated on the alkyne. These reactions proceed with excellent levels of regioselectivity. Subsequent functionalization of the isoxazole scaffold has been demonstrated.
Nitrogen isotopes are an important tool for evaluating past biogeochemical cycling from the paleoceanographic record. However, bulk sedimentary nitrogen isotope ratios, which can be determined routinely and at minimal cost, may be altered during burial and early sedimentary diagenesis, particularly outside of continental margin settings. The causes and detailed mechanisms...
The importance of spatial pattern in ecosystems has long been recognized. However, incorporating patchiness into our understanding of forces regulating ecosystems has proven challenging. We used a combination of continuously sampling moored sensors complemented by shipboard sampling to measure the temporal variation, abundance, and vertical distribution of four trophic levels...
Nearly all freshwaters and coastal zones of the US are degraded from inputs of excess reactive nitrogen (Nr), sources of which are runoff, atmospheric N deposition, and imported food and feed. Some major adverse effects include harmful algal blooms, hypoxia of fresh and coastal waters, ocean acidification, long-term harm to...
Face checking in decorative maple veneered plywood panels is a significant
problem for hardwood plywood manufacturers, furniture makers, cabinetmakers, and consumers. Efforts made by panel producers and researchers to minimize checking conducted to-‐date have been limited, and produced contradictory results. In this study the impact of four manufacturing factors believed...