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Gas phase x-ray photoelectron spectroscopy of some ketone compounds

Creator:: Situmeang, Rudy T. M.
Abstract:: The photoelectron spectra of a series of ketone compounds have been investigated in the gas phase. Core ionization energies were measured to probe the effects of molecular size and connectivity number on core ionization energies. It was found that core ionization energies roughly decrease with increasing connectivity number as expected....
Resource Type:: Masters Thesis
Full Text:: would like to express my sincerest appreciation and gratitude to Distinguished Professor T. Darrah

High-resolution X-ray photoelectron spectroscopy of CO₂ and other small molecules

Creator:: Hahne, Jeffrey A.
Abstract:: The carbon is photoelectron spectrum of CO₂ has been measured with very high photon energy resolution. The natural lifetime of the carbon is hole state has been determined from a series of spectra taken at photon energies of 308, 320, and 330 eV. The measured values of the lifetimes show...
Resource Type:: Masters Thesis
Full Text:: Photoelectron Spectroscopy of CO9 and Other Small Molecules. Abstract approved. T. Darrah Thomas The

Inner-shell lifetimes of small gas-phase molecules

Creator:: Coville, Mary
Resource Type:: Dissertation
Full Text:: Gas-Phase Molecules. Abstract approved: T. Darrah Thomas Theoretical calculations and scattered

Satellite structure in the gas-phase X-ray photoelectron spectra of planar unsaturated molecules

Creator:: Chambers, Scott Alexander
Abstract:: The satellite structure ("shake-up") present in the X-ray photoelectron spectra of several planar molecules containing double bonds has been investigated in the gas phase. This set consists of three five-membered heterocyclic molecules, ethylene and two of its fluorinated analogs, and benzene with three of its fluorinated analogs. In addition, core...
Resource Type:: Dissertation
Full Text:: Abstract approved: T. Darrah Thomas The satellite structure ("shake-up") present in the X- ray

Photoelectron spectroscopy of small molecules

Creator:: Bomben, Kenneth D.
Abstract:: The photoelectron spectra of a series of halogenated molecules have been investigated in the gas phase. Both core-ionization energies and Auger kinetic energies were measured to probe the nature of the interaction that holds a core electron to the molecule. It was found that satellite structure (shake) could be used...
Resource Type:: Dissertation
Full Text:: (T. Darrah Thomas) The photoelectron spectra of a series of halogenated molecules have been

Gas phase x-ray photoelectron spectroscopy of compounds containing multiply-bonded oxygen

Creator:: Smith, Steven Reid
Abstract:: A new x-ray source capable of operating at up to 80 watts has been designed and developed, and put to use with the Oregon State University Cylindrical Electrostatic Analyzer. The new source produces over four times the photoelectron intensity of its predecessor, from gaseous samples, and accommodates a wider selection...
Resource Type:: Dissertation
Full Text:: Privacy T. Darrah Thomas A new x-ray source capable of operating at up to 80 watts has been designed

X-ray photoelectron spectroscopy of trifluoromethylbenzenes and chlorofluoromethanes

Creator:: Holmes, Steven Allen
Abstract:: The core-electron ionization potentials for mono- and di(trifluoromethyl)benzene, for chlorofluoromethanes and for chlorine have been measured in order to give information on the electron distribution in these molecules and to investigate differences between the inductive effect of fluorine and that of CF3. For trifluoromethylbenzene the measured ionization potentials in eV...
Resource Type:: Masters Thesis
Full Text:: CHLOROFLUOROMETHANES Redacted for privacy Abstract approved: (Dr. T. Darrah Thomas) The core-electron ionization

Experimental and theoretical investigation of the ability of oxygen-containing molecules to accept charge

Creator:: Siggel, Michele Ruth Fisher
Abstract:: The question of why carboxylic acids and phenols are stronger acids than alcohols has been investigated experimentally and theoretically. The experimental approach involves comparison of gas-phase acidities and core-ionization energies. The theoretical treatment uses calculated point potentials and acidities. The ease of proton removal is related to two factors known...
Resource Type:: Dissertation
Full Text:: Redacted for privacy Abstract approved: T. Darrah Thomas The question of why carboxylic acids and phenols

The oxidation of trimethylamine by copper (II) chloride

Creator:: Lane, Thomas Alfred
Abstract:: This research was on the irreversible oxidation of trimethylamine by copper(II) chloride, which takes place at temperatures of about 75° and higher. The coordination of trimethylamine by copper(II) chloride, which is a preliminary reaction to the oxidation, was studied at 0°. The coordination of trimethylamine by the potential reduction product,...
Resource Type:: Masters Thesis
Full Text:: by the equation Fieff = 2.828 (Xcor T) 1/2, was 1.79 B. M. In pressure-composition studies, samples

Isotopic exchange reactions of hydrogen sulfide in nonaqueous solutions

Creator:: Beasley, Thomas Miles
Resource Type:: Masters Thesis
Full Text:: Nonaqueous Solutions IOOTOPIC EXCHANGE REACTIONS OF H!DROGEN SULFIDE IN NONAQUEOUS SOLUTIONS by THOMAS

ScholarsArchive@OSU

Gas phase x-ray photoelectron spectroscopy of some ketone compounds

High-resolution X-ray photoelectron spectroscopy of CO₂ and other small molecules

Inner-shell lifetimes of small gas-phase molecules

Satellite structure in the gas-phase X-ray photoelectron spectra of planar unsaturated molecules

Photoelectron spectroscopy of small molecules

Gas phase x-ray photoelectron spectroscopy of compounds containing multiply-bonded oxygen

X-ray photoelectron spectroscopy of trifluoromethylbenzenes and chlorofluoromethanes

Experimental and theoretical investigation of the ability of oxygen-containing molecules to accept charge

The oxidation of trimethylamine by copper (II) chloride

Isotopic exchange reactions of hydrogen sulfide in nonaqueous solutions

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