Verrucarol is the sesquiterpene portion of a number of macrocyclic di- and triesters of potential medicinal importance. In this study, a novel approach to the synthesis of this fungal metabolite is presented. An A-B-C route was investigated in which C-3 and C-4 of the C-ring were emplaced using a [2+2]...
The adsorption of uranium ions from seawater could be of importance
as reserves of uranium are depleted. The structure, chemical
state, and concentration of uranium in seawater have been previously
determined. Uranium exists as a charged ion, UO₂(CO₃)₃⁴⁻. The concentration
in seawater is 3.3 parts per billion.
Previous studies with...
The core-electron ionization potentials for mono- and
di(trifluoromethyl)benzene, for chlorofluoromethanes and for
chlorine have been measured in order to give information on
the electron distribution in these molecules and to investigate
differences between the inductive effect of fluorine
and that of CF3. For trifluoromethylbenzene the measured
ionization potentials in eV...
Lamellar x-ray diffraction was studied from thin films of L-α-1,2-dipalmitoyl lecithin (DPL) and a 1:1 mixture (BrDPL) of L-α-l-palmitoyl-2-(9- bromopaimitoyl) lecithin and its 10-bromo analog. The specimens had high lamellar order, with an upper bound on the mosaicity of 6 mrad (0.4°) for DPL and BrDPL. With various water contents,...
Metal-oxo clusters are discrete molecular metal-oxides. Most metals form numerous cluster compounds that can be ligated, unligated, charged or neutral, controlling their solubility in water and/or organic solvents. They are important species to study reaction pathways from the monomeric building units to the bulk metal oxides, and have many application...
Basalts of both Eocene and Miocene age from several groups
along the Oregon and Washington coasts have been analyzed for some
major, minor, and trace elements using instrumental neutron activation analysis (INAA). The rare earth element (REE) patterns observed
in these samples are used for comparisons within the groups studied...
The incorporation of europium and dysprosium in potassium
chloride crystals was investigated. The crystals were prepared by
the Kyropoulos method from melts containing the rare-earth chlorides.
The concentration of these rare-earth ions in the crystals was determined
by neutron-activation analysis. The distribution coefficient of
europium and dysprosium between the molten...
Polyoxometalates are a rapidly growing class of discrete metal oxide clusters with a wide range of applications including functional materials. These anionic clusters of the group V and VI transition metals are inexpensive and non-toxic. Within group V polyoxometalates, niobium and tantalum chemistry has been underdeveloped owing to their unique...