Polyoxometalates are discrete anionic oxo clusters of the Group V and VI transition metals that can be conceptualized as molecular metal oxides. Because they are pairable with any alkali cation, a great deal of fundamental chemistry can be gleaned from their study, including solubility trends and insight into cation binding...
In situ, reduction of Cp*ReO₃ by PPh₃ to form (Cp*ReO)₂(μ-O)₂ allows catalytic deoxygenation of epoxides, however, conproportionation between Reⱽ and Reⱽᴵᴵ species to form clusters of ((Cp*Re)₃(μ-O)₆}²⁺(ReO₄⁻)2 and new compound {(Cp*Re)₃(μ²-O)₃(μ³-O⁾³ReO₃}⁺(ReO₄⁻) leads to removal of rhenium from the catalytic cycle and loss of activity, The epoxide deoxygenation mediated by (Cp*ReO)₂(μ-O)₂...
The
purpose
of
this
study
was
to
characterize
the
neutral
lipids
of
the
fat
body
of
the
larva
of
the
fleshfly
Sarcophaga
bullata
and
to
examine
the
means
by
which
these
lipids
are
synthesized.
The
weight
of
the
larva,
the
fat
body
as
well
as
its
lipid
content
were
examined...
The migration of chloride ions in concrete with steel reinforcement under cathodic protection was investigated. Mortar blocks (15 cm x 15 cm x 17 cm) of various composition (water to cement ratio, chloride ion content) were cast with an iron mesh cathode embedded along one face and a thermally sprayed...
Acetylbenzoyl reacted with dimethylamine hydrochloride
and benzaldehyde in primary isoamyl alcohol under
reflux conditions to form 1,4-diphenvl-3-butene-1,2-dione,
compound I, which melted at 56-57°C.
Compound I formed a quinoxaline derivative, compound
II, which melted at 152.5-153°C.
Compound I was cleaved by hydrogen peroxide to form
cinnamic acid, compound III, which melted...