Index Catalog // ScholarsArchive@OSU

Exploratory studies of the mechanism of 1,3 sigmatropic ring expansion reactions

Creator:: James, Corinne Patricia
Abstract:: The potassium salts of certain 1-vinylcycloalk-3-en-l-ols have been found to undergo sigmatropic ring expansion rearrangements in HMPA. Preliminary investigations of several benzo-substituted medium ring systems were undertaken in order to determine which of these was best suited for further study. A synthetic sequence leading to the formation of 5-methy1-6-viny1-7,8,9,10-tetrahydro-6-benzocyclo-octenol, which...
Resource Type:: Masters Thesis
Full Text:: ring expansion reactions AN ABSTRACT OF THE THESIS OF Corinne James for the degree of Master of

Siloxy-cope and oxy-cope rearrangements of the cis- and trans-1-vinylcyclodec-3-en-1-ol systems ; Acid-catalyzed rearrangement of cis-bicyclo [6.1.0] nonane-cis- and trans-9-methanols ; An effective two-carbon ring-expansion

Creator:: Billigmeier, James Earl
Resource Type:: Dissertation
Full Text:: - and trans-9-methanols ; An effective two-carbon ring-expansion AN ABSTRACT OF THE THESIS OF James

Kinetics and mechanisms of nucleophilic displacement reactions with S-methyl-S-phenyl-sulfiminium perchlorate

Creator:: KiYokane, Richard Junji
Resource Type:: Masters Thesis
Full Text:: AN ABSTRACT OF THE THESIS OF Richard Junji Kiyokane for the

Cyclization of olefinic β-ketoesters. An approach to the synthesis of aplysistatin

Creator:: Skeean, Richard William
Resource Type:: Dissertation
Full Text:: for Richard W. Skeean iv AKNOWLEDGEMENTS I wish to thank Dr. James D. White for his support and

Geochemical study of Hawaiian basalts

Creator:: Budahn, James Richard
Resource Type:: Masters Thesis
Full Text:: THE THESIS OF JAMES RICHARD BUDAHN for the degree of MASTER OF SCIENCE (Name of student) (Degree) in

A quantitative description of the silver/aqueous cyanide electrolyte interface and the effect of the interface on the rate of electrodeposition of silver

Creator:: Jewett, James Richard
Resource Type:: Dissertation
Full Text:: AN ABSTRACT OF THE THESIS OF James Richard Jewett for the

The synthesis and characterization of novel materials for use in secondary lithium-ion batteries

Creator:: Nafshun, Richard L.
Resource Type:: Dissertation
Full Text:: use in secondary lithium-ion batteries AN ABSTRACT OF THE THESIS OF Richard L. Nafshun for the

Synthesis and oligomerization of Delta, 4-diamino-2-oxo-1(2H)-pyrimidinehexanoic acid

Creator:: Huang, Sung-ben
Resource Type:: Dissertation
Full Text:: also like to thank Dr. Richard W. Thies, Christopher K. Mathews, James H. Krueger, and Austin W

Oxy-Cope, and Siloxy-Cope rearrangement of cis-1-vinylcyclooct-3-en-1-ol

Creator:: Chin, Alice Wai-lee
Abstract:: Both oxy-Cope and siloxy-Cope rearrangements involve (1, 3) and (3, 3) sigrnatropic shifts. Both the concerted mechanism, and the stepwise mechanism via a diradical intermediate are possible. In a cyclic system such as cis-l-vinylcyclooct-3-en-l-ol, the thermal rearrangement takes place preferably through a diradical intermediate. At high temperature, the reaction also...
Resource Type:: Masters Thesis
Full Text:: Rearrangement of cis-l-vinyl- cyclooc t-3 -en -I .ol, Abstract approved: Redacted for Privacy Dr. Richard W

A pyrolysis of cis-1-trimethylsiloxy-1-cyclopropyl-3-cyclononene : the thermal isomerization of 2-phenyl-1-trimethylsiloxy-1-vinylcyclononane

Creator:: Choi, Young Bok
Abstract:: Part 1 The pyrolysis of cis-1-trimethylsiloxy-1-cyclopr opyl-3-cyclononene in the temperature range 285-350° is described. Instead of siloxy-Cope rearrangement, undesired desiloxylation took place. Part 2 Gas-phase pyrolytic rearrangement of 2-phenyl-1-trimethylsiloxy-1-vinylcyclononane was investigated in a static system in the temperature range 213-330°. It was discovered that three major products resulted: cis- and...
Resource Type:: Masters Thesis
Full Text:: Redacted for privacy Dr. Richard W. Thies The pyrolysis of cis -1 tr imethyls iloxy- 1 - cyclopr opyl- 3

ScholarsArchive@OSU

Exploratory studies of the mechanism of 1,3 sigmatropic ring expansion reactions

Siloxy-cope and oxy-cope rearrangements of the cis- and trans-1-vinylcyclodec-3-en-1-ol systems ; Acid-catalyzed rearrangement of cis-bicyclo [6.1.0] nonane-cis- and trans-9-methanols ; An effective two-carbon ring-expansion

Kinetics and mechanisms of nucleophilic displacement reactions with S-methyl-S-phenyl-sulfiminium perchlorate

Cyclization of olefinic β-ketoesters. An approach to the synthesis of aplysistatin

Geochemical study of Hawaiian basalts

A quantitative description of the silver/aqueous cyanide electrolyte interface and the effect of the interface on the rate of electrodeposition of silver

The synthesis and characterization of novel materials for use in secondary lithium-ion batteries

Synthesis and oligomerization of Delta, 4-diamino-2-oxo-1(2H)-pyrimidinehexanoic acid

Oxy-Cope, and Siloxy-Cope rearrangement of cis-1-vinylcyclooct-3-en-1-ol

A pyrolysis of cis-1-trimethylsiloxy-1-cyclopropyl-3-cyclononene : the thermal isomerization of 2-phenyl-1-trimethylsiloxy-1-vinylcyclononane

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