An important aspect in device technology is the
processing of GaAs to produce highly-resolved etch
patterns on the substrate. This is done typically on the
GaAs(100) surface. Recently, a number of methods, all
using chlorinated vapor reactants, have been applied to
fabrication of GaAs devices. In spite of these
technological...
Neurofilament proteins are intermediate filaments found in the neuronal cytoskeleton. Phosphorylation of these proteins is considered important for the assembly and stability of the filaments. Accurate molecular weights have been difficult to measure, largely because the high degree of phosphorylation results in M[subscript r]'S that are significantly greater than dictated...
The central purpose of this dissertation was to explore and expand the use of
an uniform electric field for orientation and for subsequent spectroscopic investigation of asymmetric polar molecules in the gas phase. The systems of study were nitrobenzene (NB) and the nitrotoluene (NT) isomers. We were able to quantitatively...
The fragmentation characteristics of protonated peptides have been investigated using
tandem mass spectrometry (MS/MS) under various fragmentation regimes and detailed
density functional theory (DFT) reaction pathway calculations. The DFT calculations
predict novel salt-bridge stabilized transition structures as well as consecutive reactions
occurring in proton-bound dimers for some of the ions...
The temporal and spatial characteristics of the plume produced
by a laser microprobe, are dependent upon the composition and pressure
of the atmosphere surrounding it. It has been shown that certain atmospheres
can enhance the analytical signal by increasing the free
atom lifetime.
Improvements were made to the existing laser...