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Hydrogen abstraction from substituted t-butylbenzenes

Creator:: Harvey, Robert Louis
Abstract:: A study of the relative rates of the alkyl hydrogen abstraction from a series of meta and para substituted t-butylbenzenes by the chlorine atom at 70°C has been carried out. Application of the Hammett equation yielded a ρ value of -0.44 for the para compounds. Possible explanations for the non-linearity...
Resource Type:: Masters Thesis
Full Text:: ABSTRACT OF THE THESIS OF ROBERT LOUIS HARVEY for the Master of Science (Name of Student) in Chemistry

Simultaneous spectrophotometric determination of barium and strontium using sulfonazo III

Creator:: Kemp, Paul James
Abstract:: A simultaneous direct spectrophotometric method for the determination of barium and strontium using Sulfonazo III has been developed making use of the chelons EGTA and CDTA at controlled pH values. An absorbance study of the barium and strontium complexes of Sulfonazo III revealed that there is no pH sensitivity of...
Resource Type:: Masters Thesis
Full Text:: SPECTROPHOTOMETRIC DETERMINATION OF BARIUM AND STRONTIUM USING SULFONAZO III Abstract approved: Max B. Williams A

Investigation of the complexes of 3-(2-arsonophenylazo)-4,5-dihydroxy-2, 7-naphthalenedisulfonic acid, "arsenazo," with alkaline earths

Creator:: Warren, Herbert Dale
Resource Type:: Dissertation
Full Text:: wishes to express his gratitude to Dr. Max B. Williams who has directed much of the work described in

A mechanistic study of the distribution of amphiphilic organic compounds between water and organic sorbents

Creator:: Zhang, Wanjia
Resource Type:: Dissertation
Full Text:: for Privacy Abstract approved: John C. Westall This study was conducted to elucidate some factors

Computational Investigations of Transition Metal Catalyses and Amorphous Metal Oxides : Accelerating Scientific Discovery Through Automation

Creator:: Mustard, Thomas J. L.
Abstract:: Automation of computational chemistry, while only an engineering feat, has the potential to accelerating computational research be removing all by the science. The work in this thesis mainly discusses fundamental understanding of complex chemical systems. What is not obvious are the numerous tasks necessary for this fundamental understanding. Under the...
Resource Type:: Dissertation
Full Text:: my committee members, Professor Rich Carter, Professor Doug Keszler, Professor John Wager, and

Fate and transport of the surfactant linear alkylbenzenesulfonate in a sewage-contaminated aquifer

Creator:: Krueger, Carolyn J.
Abstract:: Linear alkylbenzenesulfonate (LAS) is the most widely used anionic surfactant in commercial detergent formulations. The environmental fate of LAS is of interest because of its disposal to wastewater treatment facilities and subsequent occurrence as a micropollutant in surface waters and groundwater. While LAS fate in wastewater treatment systems and surface...
Resource Type:: Dissertation
Full Text:: . Ten.side Surfactants Deterg. 1985, 22, 299. (28) Hand, V. C.; Williams, G. K. Environ. Sci. Technol. 1987

The photochemical transformation of oxime carbamates

Creator:: Ndip, Edmund Moses Nso
Resource Type:: Masters Thesis
Full Text:: Calabarians of Nigeria (5). It was not until 1864 that the active compound, eserine (2) was isolated and its

Lattice effects of lithium hydroxide : isotopic effects and factor group analysis

Creator:: Lilley, Suetta Albin
Abstract:: The infrared absorption spectrum from 3200 cm⁻¹ to 4025 cm⁻¹ of thin crystals of ⁶LiOH (99%⁶Li.) is presented and compared to the spectrum of [superscript]NLiOH (93%⁷Li). A shift in only one of the band pairs supports the lattice combinations model and assists in making assignments for the major features of...
Resource Type:: Masters Thesis
Full Text:: . Journal of Chemical Physics 43: 1864-1869. 1965. 25. Phillips, Betty A. and William R. Busing. Comparison

The photodecomposition of t-butyl bicyclo [7.1.0] decane-2-percarboxylate

Creator:: McRitchie, Donna Louise
Abstract:: This paper describes the synthesis of t-butyl bicyclo[7.1.0] decane-2-percarboxylate and its photolytic decomposition. The title compound was found to undergo simple homolytic cleavage when exposed to light of 2537 A; producing the cyclodecyl radical, carbon dioxide, and t-butoxy radical. The largest percentage of products arose from an intimate radical pair...
Resource Type:: Masters Thesis

Oxidation of ethanol and phenols with permanganate for chemiluminescence analysis

Creator:: Al-Mutawah, Jameela Isa
Resource Type:: Masters Thesis
Full Text:: . Columbus (1446-1506) and John Davis (1550-1603) referred to a light, which may have been the luminous

ScholarsArchive@OSU

Hydrogen abstraction from substituted t-butylbenzenes

Simultaneous spectrophotometric determination of barium and strontium using sulfonazo III

Investigation of the complexes of 3-(2-arsonophenylazo)-4,5-dihydroxy-2, 7-naphthalenedisulfonic acid, "arsenazo," with alkaline earths

A mechanistic study of the distribution of amphiphilic organic compounds between water and organic sorbents

Computational Investigations of Transition Metal Catalyses and Amorphous Metal Oxides : Accelerating Scientific Discovery Through Automation

Fate and transport of the surfactant linear alkylbenzenesulfonate in a sewage-contaminated aquifer

The photochemical transformation of oxime carbamates

Lattice effects of lithium hydroxide : isotopic effects and factor group analysis

The photodecomposition of t-butyl bicyclo [7.1.0] decane-2-percarboxylate

Oxidation of ethanol and phenols with permanganate for chemiluminescence analysis

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