Methane derived authigenic carbonate (MDAC) precipitation occurs within marine sediments as a byproduct of the microbial anaerobic oxidation of methane (AOM). While these carbonates form in chemical and isotopic equilibrium with the fluids from which they precipitate, burial diagenesis and recrystallization can overprint these signals. Plane polarized light (PPL) and...
Quantifying the mass transport through marine sediments, and the geochemical response to such flow with numerical models has become a common and powerful approach for geochemical data interpretation. In this dissertation, I developed and applied transport-reaction models to unravel complex and interdependent reactions involving carbon, sulfur and silica transformations in...
Large barite (BaSO4) structures mark cold seeps in the southern San Clemente Basin. Barium flux to San Clemente sediments is two to three times greater than fluxes measured in surrounding California Borderland basins. Analyses of sediment trap material, water column samples, sediments and pore water indicate that expected bariumbearing mineral...
We present a new nitrogen isotope model incorporated into the three-dimensional ocean component of a global Earth System Climate Model designed for millennial timescale simulations. The model includes prognostic tracers for the stable nitrogen isotopes, ¹⁴N and ¹⁵N, in the nitrate (NO₃ˉ), phytoplankton, zooplankton, and detritus variables of the marine...
Marine sediments contain an abundance of methane that is biologically produced
and plays a significant role in the global carbon cycle. Microbes responsible for the
carbon cycle in marine sediments, and the processes that they carry out, need to be
characterized in order to fully understand the role of this...
Two separate research projects are described here. One involves
development of a new analytical method for determination of Ba in seawater and
other natural waters. The other is a collaborative field study of the chemistry of
Lake Issyk-Kul, Kyrgyzstan.
The method project explored an ion chromatography-fluorescence detection
bench-top approach for...
Physical-biological interactions in the Southern Ocean were investigated using remote sensing data from several different satellite sensors. Satellite sea surface temperature data were used to study the dynamics of the Antarctic Polar Front (PF). Satellite ocean color data were used to estimate surface chlorophyll concentrations and their relation to various...