Attempts to synthesize diboron tetrafluoride by the reduction of
boron trifluoride with alkali metal solutions in 1, 2-dimethoxyethane
proved to be unsuccessful. No diboron tetrahalide was found when
boron trifluoride, antimony trifluoride, or boron trichloride was
reacted with tetra-(dimethylamino)-diboron; although there appeared
to be some exchange between chloride and amine...
The inhibition of the enolase enzyme system by fluoride has
been established for many years in in vitro experiments; however,
this inhibitory action has never been demonstrated in an intact mammal.
The present work was designed to examine the effect of fluoride
administered by intravenous infusion in rats, under the...
New chemical synthesis strategies have been investigated for the preparation of acceptor-type graphite intercalation compounds (GIC's) with fluoroanions in order to obtain new materials and to develop a better understanding of the synthetic approaches and properties of the products. New GIC's containing borate chelate anion such as bis(oxalato)borate, CxB[OC(O)C(O)O]₂•δF, are...
New acceptor-type graphite intercalation compounds (GICs) containing perfluoroalkyl anions have been synthesized by using both chemical and electrochemical methods and characterized by elemental and thermogravimetric analyses. Investigation into these graphite intercalation compounds can provide novel materials and a detailed understanding of their properties.
GICs of composition Cx[FB(C₂F₅)₃]·δF are prepared for...