This thesis investigates the influence of early diagenesis on trace metal and
molybdenum isotope behavior in marine and lacustrine environments. Chapter one is a
synthesis of previous research in all the marine environments investigated, providing an
essential geochemical context for interpreting the observed behavior of Mo in these settings.
Chapter...
Ocean circulation is an important component in Earth's climate system. Predicting future climate and circulation changes requires an improved understanding of the past relationship between climate and ocean currents. The neodymium isotope composition (εNd) of water masses is frequently used as a quasi-conservative tracer to reconstruct ocean circulation. The current...
New chemical synthesis strategies have been investigated for the preparation of acceptor-type graphite intercalation compounds (GIC's) with fluoroanions in order to obtain new materials and to develop a better understanding of the synthetic approaches and properties of the products. New GIC's containing borate chelate anion such as bis(oxalato)borate, CxB[OC(O)C(O)O]₂•δF, are...
This dissertation works towards determining the mechanisms driving the Mo isotopic composition of soils, and how these signals may be used to refine the use of Mo as a proxy of biogeochemical processes. The first step towards quantifying Mo fractionation in soils is to determine the mechanisms controlling Mo accumulation,...
This thesis presents the results of a formal evaluation of a new AOGCM, GENMOM, demonstrating its ability to simulate present-day climate and ENSO dynamics. The model is applied to simulate climate for the Last Glacial Maximum, deglacial, and Holocene time periods. The model output is evaluated against the best available...
The central purposes of this study were to review the
historical sources of David Kolb's formulation of experiential
learning theory, and to determine the effect and
application of Kolb's theory and Learning Style Inventory
as reflected in the literature between 1971 and 1990.
It was found that Kolb based his...
The rare earth elements (REEs) have been established as powerful tracers for a range of physiochemical processes occurring in the natural environment. They also hold significant economic importance as many technological advancements are reliant upon the REEs for their unique magnetic, luminescent, and electrochemical characteristics. In sedimentary settings, understanding the...
A benthic microbial fuel cell (BMFC) is an electrochemical device that
generates current from the redox gradient at the sediment-water interface. Early
prototypes had anodes buried in anoxic sediments and cathodes in overlying water.
The BMFCs described in this dissertation are based on a chamber design that enables
the use...
This thesis investigates the behavior of major inorganic nutrients (P, N, Si), trace metals (Mn, Fe), and alkaline-earth metals (Ba) within Tillamook Bay over seasonal cycles and under a range of river discharge conditions from October 1997 through December 1999. Located in the Pacific Northwest region, Tillamook Bay is an...