Frontier research of non-aqueous actinide clusters is discussed. Since the inception of the uranyl peroxide clusters over the last decade, they have only been synthesized and characterized as solid crystals and in aqueous solution. This thesis provides thorough characterization of aqueous uranyl clusters and the first demonstration of uranyl cluster...
Polyoxometalates are discrete anionic oxo clusters of the Group V and VI transition metals that can be conceptualized as molecular metal oxides. Because they are pairable with any alkali cation, a great deal of fundamental chemistry can be gleaned from their study, including solubility trends and insight into cation binding...
Geologic CO₂ sequestration is a climate change mitigation strategy that prevents CO₂ emissions to the atmosphere by capturing CO₂ gasses from large point source emissions streams and then pressurizing and pumping the supercritical-state CO₂ into underground geologic storage reservoirs. Once underground, CO₂ is prevented from buoyant migration to the surface...