We report vibrational information of both the first electronically excited state and the ground
cationic state of jet-cooled triphenylene via the techniques of resonantly enhanced multiphoton
ionization (REMPI) and zero kinetic energy (ZEKE) photoelectron spectroscopy. The first excited
electronic state S₁ of the neutral molecule is of A₁' symmetry and...
We report zero kinetic energy (ZEKE) photoelectron spectroscopy of benzo[a]pyrene (BaP) via resonantly enhanced multiphoton ionization (REMPI). Our analysis concentrates on the vibrational modes of the first excited state (S₁) and those of the ground cationic state (D₀). Similar to pyrene, another peri-condensed polycyclic aromatic hydrocarbon we have investigated, the...
We report zero kinetic energy (ZEKE) photoelectron spectroscopy of benzo[h]quinoline (BhQ) via resonantly enhanced multiphoton ionization (REMPI) through the first electronically excited state S₁. From the simulated REMPI spectra with and without Herzberg–Teller coupling, we conclude that vibronic coupling plays a minor but observable role in the electronic excitation to...
Just as Pirsig’s (Pirsig, R.M. 1974. Zen and the Art of Motorcycle Maintenance. William Morrow and Company, New York. 412pp.) account of his motorcycle adventure explores the dichotomy of holistic and reductionistic philosophies, so too does a short course in chainsaw safety and tree felling incorporate these seemingly disparate viewpoints...
The zebrafish (Danio rerio) is emerging as a new important species for studying brain mechanisms and its deficits. Focusing on selected CNS disorders (brain cancer, epilepsy and anxiety) and using them as examples, we discuss the value of zebrafish models in translational neuroscience, and their contribution to neuroimaging, circuit-level and...
Cytokinins are a group of plant hormones mediating cell division and
differentiation. Zeatin is a naturally occurring and highly active cytokinin that is rapidly
metabolized in Phaseolus seeds. The metabolites and enzymes mediating the conversion
have been studied extensively. Zeatin metabolic enzymes may be utilized in studying the
regulation of...
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