Two-phase gas-liquid flows in microscale fractal-like branching channel flow networks were experimentally studied to assess the validity of existing void fraction correlations and flow regimes based on superficial gas and liquid velocities. Void fractions were assessed using two different methods. First, void fraction data were acquired using a High-Speed-High-Resolution (HSHR)...
Two studies were conducted to determine the effect of varying vitamin B-6 (B- 6) status on lymphocyte mitogenic response and pyridoxal 5'-phosphate (PLP) concentration in peripheral blood mononuclear cells (PBMC) in young women. In the first study, women were fed 1 mg/d for the first week and 1.5, 2.1 and...
As the performance gap between processor and memory grows, memory latency will be a major bottleneck in achieving high processor utilization. Multithreading has emerged as one of the most promising and exciting techniques used to tolerate memory latency by exploiting thread-level parallelism. The question however remains as to how effective...
The construction industry is one of the largest sectors in the U.S. economy, yet little is known about the
key macroeconomic parameters that affect its industry’s structure and performance. The main objectives
of this research are 1) to analyze the macroeconomic performance of construction industry as a whole and
at...
Part of the Y chromosome in humans is detectable as a brightly
fluorescing body in interphase nuclei stained with quinacrine dyes.
This fluorescent body when stained with quinacrine mustard dihydrochloride,
in cells from some 15 human subjects, was seen to manifest
a variable morphology which appeared to be related to...
The genetic aspects of population health are critical, but frequently difficult to assess. Of concern has been the genetic constitution of Scandinavian wolves (Canis lupus), which represent an important case in conservation. We examined the incidence of different congenital anomalies for 171 Scandinavian wolves, including the immigrant founder female, born...
Y-Zeolite catalysts have the potential to promote the
shape-selective conversion of glucose to oxygenated
hydrocarbons at fairly low temperature (100 to 130°C).
Reaction of glucose solution with H-Y Zeolite catalyst
powder was carried out in a well-mixed batch reactor. This
reaction was studied as a function of reaction time (0...
In this report, three studies are presented that utilize computations to predict transformations, identities, and properties of environmental organic molecules. Each study shows how computations can lead to models of chemical behavior. The importance of this research is rooted in the need for understanding how human behavior and health intersect...
My work has focused on investigating synthetic organic reactions using applied computational methods. Non-covalent interactions are critical to catalysis, mechanism, and stereoselectivity, with the most prominent interaction for isothioureas being the S···O contact between the catalyst sulfur atom and the oxygen of the acyl group. A comprehensive joint experimental and...
Complex organic transformations, such as the addition of pyrrole to ketene using planar chiral organocatalyst (*PPY), the four-component anhydride- Manniach reactions, and the site-selective desymmetrization of meso-1,2-diol, are remarkable synthetic reactions that provide high yield and high selectivity. However, the exact mechanism and origins of stereocontrol for theses synthetic organic...