Dielectric ceramics designed for capacitor applications for use in extreme environments, such as high temperatures, high voltages, or high-pressure environments, are in great demand. Existing capacitor technology fails to perform within these extreme conditions or such environments. The development of new dielectric ceramic materials for high temperature capacitor applications is...
Relaxor characteristic of the solid solution (1-x)BaTiO₃-(x)Bi(Zn₁/₂Ti₁/₂)O₃ (BTBZT) was investigated in this research. X-ray diffraction technique and Raman spectroscopy revealed the crystal structure of BT-BZT at various compositions. For compositions with x ≤ 0.08, the solid solutions exhibited clear tetragonal symmetry and transitioned to pseudo-cubic symmetry as the content of...
Lead zirconate titanate (PZT) is the dominant ferroelectric material in the market due to its excellent piezoelectric properties, relatively high Curie transition temperature (T[subscript C]), low cost, etc. However, because of emerging applications with requirements for high temperature (T[subscript C] > 400 °C) ferroelectrics, researchers are increasingly looking at alternative...
The aim of this research is to develop a fundamental understanding of the dominant defect species and the relevant defect equilibrium conditions for bismuth-containing perovskites to help guide the development of these materials for emerging applications. This is of paramount importance for many demanding applications, because ultimately the defect equilibria...
Since its discovery, the anomalous dielectric behavior of CaCu₃Ti₄O₁₂ (CCTO)
has drawn a great deal of attention for many possible applications in electronic
devices. The origin of the giant dielectric constant in CCTO was explained via an
internal barrier layer capacitor model, and it has been reported that the dielectric...
Much recent research has focused on the development lead-free perovskite piezoelectrics as environmentally compatible alternatives to lead zirconate titanate (PZT). Two main categories of lead free perovskite piezoelectric ceramic systems were investigated as potential replacements to lead zirconate titanate (PZT) for actuator devices. First, solid solutions based on Li, Ta,...
This dissertation demonstrated that the electrical properties of complex oxide-based perovskite materials could be controlled through the careful modification of both material composition and structure. This was first shown through the modification of lead zirconate titanate (Pb(Zr0.52Ti0.48)O3, PZT) solid solutions with bismuth indate (BiInO3, BI) where the relative stability of...
It has been well established that ferroelectric to relaxor crossover in piezoelectric ceramics exhibit promising electromechanical and dielectric properties over a wide temperature range, applying sensors and actuators transducers and such. A plethora of research has reported giant strain in various lead-free piezoelectric ceramics and attributed the reasoning to the...
The role of A-site non-stoichiometry was investigated in lead-free piezoelectric ceramics based on compositions in the 1-x(Bi₀.₅Na₀.₅TiO₃)-xBaTiO₃ system near the morphotropic phase boundary where x = 0.055, 0.06 and 0.07. The samples were prepared by a conventional solid state mixed oxide route with the A- site stoichiometry modified to incorporate...
A new group of lead free piezoelectric perovskite solid solutions, (1-x)Bi(B'B")O₃-xABO₃, were obtained via solid-state processing techniques. The solubility of unstable perovskite Bi(B'B")O₃ compounds into stable perovskite compounds was found to be related to the tolerance factor of the ABO₃ perovskite endmembers. The morphotropic phase boundary (MBP) in perovskite solid...