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Reactive intermediates in the tetracyclo-[3.3.0.0² ⁷.0⁴ ⁶] octane, the tetracyclo-[3.3.0.0² ⁴.0³ ⁷] octane, and related ring systems containing the norbornane skeleton

Creator:: Ziebarth, Timothy Dean
Resource Type:: Dissertation
Full Text:: Privacy pp Dr. Peter K. Freeman The base induced thermal decompositions of tricyclo- [3.2.1.03'6]octan

Reactive intermediates in the tricyclo- [3.2.1.0²,⁴] octane ring system

Creator:: Raghavan, Ramaswamy Srinivasa, 1941-
Resource Type:: Dissertation
Full Text:: SYSTEM Abstract approved Redacted for Privacy Dr. Peter K. Freeman An investigation of some potential

Carbonium ion intermediates in the tetracyclo [4,3.0.0²[superscript ,]⁴.0³[superscript ,]⁷] and tetracyclo [4.3.0.0²[superscript ,]⁴.0³[superscript ,]⁸] - nonane ring systems

Creator:: Stevenson, Brian Keith
Resource Type:: Dissertation
Full Text:: ' 4. 03' 8]- NONANE RING SYSTEMS Redacted for Privacy Abstract approved: . Peter K. Freeman The

Divalent carbon intermediates in some bridged polycyclic compounds

Creator:: Hardy, Thomas A.
Resource Type:: Dissertation
Full Text:: The author would like to thank Dr. Peter K. Freeman for his guidance, inspiration, and most of all

Radical anions, radicals and anions : the formation and stereochemistry of alkyl lithium reagents from lithium 4, 4'-Di-tert-butylbiphenyl and alkyl halides

Creator:: Hutchinson, Larry Lee
Resource Type:: Dissertation
Full Text:: approved: ,Redacted for Privacy. Peter K. Freeman The reactions of alkyl halides with metals and radical

The use of the Diels-Alder reaction in asymmetric synthesis

Creator:: Dei Rossi, Dale Raymond
Abstract:: The Diels-Alder reaction represents a promising tool for use in asymmetric synthesis. The reaction involves a rigid transition state that facilitates the formation of one diastereomeric transition state and is reversible. This satisfies two necessary criteria for asymmetric synthesis. The Diels-Alder reactions of 1,l-dialkylspiro[2.4]-4,6- heptadienes with maleic anhydride and p-benzoquinone...
Resource Type:: Masters Thesis
Full Text:: Abstract Approved: Redacted for Privacy Peter K. Freeman The Diels-Alder reaction represents a promising

Carbene chemistry : I. Stereochemical integrity at Cα in ketone tosylhydrazones : II. Hydrogen migration in 2-carbena-6, 6-dimethylnorbornane

Creator:: Balyeat, John Robert
Abstract:: The tosylhydrazones of exo-3-deuteriocamphor and 2- deuterio-2,4-dimethy1-3-pentanone were treated with Nbromosuccinimide (NBS) and pyruvic acid to regenerate the parent ketones. The ketones from the pyruvic acid cleavage show a significant loss of deuterium. The ketones from the NBS cleavage show no loss of deuterium, indicating that stereochemical integrity at. C[subscript...
Resource Type:: Masters Thesis
Full Text:: -DIMETHYLNORBORNANE Redacted for Privacy Abstract approved: Dr. Peter K. Freeman The tosylhydrazones of exo-3

The photochemistry of some O-(methylcarbamoyl) oximes

Creator:: McCarthy, Kermit D.
Abstract:: The photochemistry of aldicarb and two related compounds, 0-(methylcarbamoyl) isobutyraldehyde oxime and 0-(methylcarbamoyl) trimethylacetaldehyde oxime was explored under laboratory conditions. Upon irradiation aldicarb decomposed rapidly to methylamine, dimethylamine, tetramethylsuccinonitrile, and 1-methylthio-2, 3-dicyano-2, 3-dimethylbutane. The other two compounds decomposed only after a long period of irradiation. The difference in reactivity was...
Resource Type:: Masters Thesis
Full Text:: approved: Redacted for Privacy Dr. Peter K. Freeman The photochemistry of aldicarb and two related

The heteroatom effect in intramolecular cyclizations of organoaluminum and -lithium compounds

Creator:: Smith, Michael James
Abstract:: Intramolecular cyclization of organometallic compounds represents a promising tool for synthesis in general. The use of strategically- placed heteroatoms in the cyclizing molecule can influence the stereochemistry and/or efficiency of an organometallic cyclization while providing for functionality in the cyclic product. The work described herein first concerns cyclizations of organolithiums....
Resource Type:: Dissertation
Full Text:: : Peter K. Freeman Intramolecular cyclization of organometallic compounds repre- sents a promising tool

Vinylcarbene intermediates in some cyclic systems

Creator:: Swenson, Karl Edward
Resource Type:: Dissertation
Full Text:: thank Dr. Peter K. Freeman for his guidance and patience, his fellow graduate students for their

ScholarsArchive@OSU

Reactive intermediates in the tetracyclo-[3.3.0.0² ⁷.0⁴ ⁶] octane, the tetracyclo-[3.3.0.0² ⁴.0³ ⁷] octane, and related ring systems containing the norbornane skeleton

Reactive intermediates in the tricyclo- [3.2.1.0²,⁴] octane ring system

Carbonium ion intermediates in the tetracyclo [4,3.0.0²[superscript ,]⁴.0³[superscript ,]⁷] and tetracyclo [4.3.0.0²[superscript ,]⁴.0³[superscript ,]⁸] - nonane ring systems

Divalent carbon intermediates in some bridged polycyclic compounds

Radical anions, radicals and anions : the formation and stereochemistry of alkyl lithium reagents from lithium 4, 4'-Di-tert-butylbiphenyl and alkyl halides

The use of the Diels-Alder reaction in asymmetric synthesis

Carbene chemistry : I. Stereochemical integrity at Cα in ketone tosylhydrazones : II. Hydrogen migration in 2-carbena-6, 6-dimethylnorbornane

The photochemistry of some O-(methylcarbamoyl) oximes

The heteroatom effect in intramolecular cyclizations of organoaluminum and -lithium compounds

Vinylcarbene intermediates in some cyclic systems

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