The influence of shear rate and temperature on the viscosity and fragility of the Zr₄₁.₂Ti₁₃.₈Cu₁₂.₅Ni₁₀.₀Be₂₂.₅ (Vit1) metallic glass forming liquid is measured in the liquid and undercooled liquid state between 907 and 1300 K. The results show a complex rheological behavior of Vit1. The viscosity of Vit1 is about three...
Amorphous multicomponent metals have promising applications in novel electronic devices because of their atomically smooth surface morphology and lack of grain boundaries. It is important to understand the thermal transport properties of amorphous metals and an accurate measurement of their thermal conductivity will be essential for further improvement of device...
The objective of this thesis is to provide an initial demonstration of two-terminal and three-terminal electronic devices employing amorphous multi-component metallic film
(AMMF) electrodes. Such a demonstration is successfully achieved in the fabrication of metal-insulator-metal (MIM) diode and hot electron transistor (HETs) structures employing ZrCuAlNi AMMF electrodes. The ultra-smooth surface...
This paper documents the investigation into injection molding, or die casting, a bulk metallic glass (BMG). A BMG is an amorphous metal of a thickness greater than 25 μm, according to leading researchers in the field. This critical thickness differentiates a normal metallic glass from a "bulk" metallic glass. The...
A high temperature high vacuum rheometer has been designed, fabricated,
and tested for the study of the steady shear viscosity for multicomponent bulk
metallic glass forming alloys. This rheometer has an operating range up to
1525 K, rotational frequencies of 9.4*10⁻³-3.7*10¹ radians/s, and a
calibrated viscosity range of 9.6*10⁻³ and...
A Bulk Metallic Glass (BMG) is an amorphous solid with thickness greater than 1mm. Material properties of BMG, like twice the strength of regular steels and excellent corrosion resistance, make them ideal materials for fabrication of MEMS and MECS devices which have attracted a lot of research activity recently. Diffusion...
The motivation for undertaking this research was to increase the understanding of processing colloidal semiconductor nanocrystals and thin films metallic glasses to enable their wider application in future devices. This research covered two unique materials, lead selenide (PbSe) nanocrystals and thin film metallic glass alloy of zirconium copper aluminum nickel...
The research presented herein represents an effort to combine the ultra-smooth surface of an amorphous metal thin film (AMTF) with a solution-processed dielectric synthesized via prompt inorganic condensation (PIC). Analysis of dielectric film quality is carried out via electrical measurements of metal-insulator-metal (MIM) diodes. Anneals at 500 and 700 °C...
Amorphous metal thin films lack the grain boundaries and dislocations present in
crystalline metal films. As a result, amorphous metal films can be more mechanically robust, atomically smooth, and more resistant to chemical attack than crystalline metals. However, amorphous metals are meta-stable and subject to crystallization upon heating, thus limiting...