A large rainfall simulator was used to study infiltration on six
soil plots. Water content and capillary pressure were measured during
steady rainfall at rates less than required to produce runoff. The
equipment and procedures used to make these measurements are discussed.
Water content and capillary pressure data obtained as...
In this research, the interfacial behavior of Trichoderma reesei CBHI and Thermomonospora fusca E₅ cellulases were studied at synthetic surfaces. For this purpose, colloidal silica and polystyrene particles were used to prepare cellulase-particle suspensions that were analyzed by several solution-phase techniques. These included circular dichroism spectroscopy, size exclusion chromatography and...
The formation of solution and solid complexes with heavy metals
will partially determine their mobility and plant availability in soil
systems. Experiments were initiated to determine the effect of pH,
adsorbent and initial metal concentrations, and the presence of water
soluble ligands on the adsorption of Cd and Cu by...
The reaction of F, often a component of industrial
wastes and phosphatic fertilizers, with soil was studied
with regard to sorption reactions and resultant changes in
solution composition. Sodium fluoride solutions (0.0 to
2.5 mmol/L F) were equilibrated with ten soils for 24h.
The soil extract solutions were analyzed for...
A Langmuir sorption model incorporating a second step of
irreversible absorption was applied to a model soil system. The column
was packed with cellulose triacetate; pulse and step input tests with
3,4-dichlorophenol were performed; the effluent concentration was
measured by electron capture detector gas chromatography and sorption
rate constants were...
Electric fields due to adsorbates on a metal surface are studied experimentally with Rydberg atoms as probes. A beam of lithium Rydberg atoms, produced by an oven in a high-vacuum system, passes within 3μm of the surface of a metal mesh having 6μm square openings. Rydberg states with principal quantum...
Chromium and its compounds are widely used by modern industries, resulting in large quantities of this element being discharged into the environment. To remove chromium from contaminated soils and ground water, it is necessary to predict chemical and physical processes that control the rate of reactions and transport of chromium...