Thin-film transistors (TFTs) are primarily used as a switching element in liquid crystal
displays. Currently, amorphous silicon is the dominant TFT technology for displays, but
higher performance TFTs will become necessary to enable ultra-definition resolution
high-frequency large-area displays. Amorphous zinc tin oxide (ZTO) TFTs were
fabricated by RF magnetron sputter...
The development of micro total analysis systems (µTAS), also called “lab-on-a-chip”, or microfluidic analysis systems, is presented in this dissertation. Various research areas, covering subjects from magnetic particles synthesis to novel microchip fabrication techniques, are explored to develop a lab-on-a-chip system capable of performing magnetic bead-based bioassays. These devices are...
There is significant interest in the fabrication of nano- and micro-structured silica with spatially ordered features, which exhibit enhanced optoelectronic properties with application to the next generation of display devices, semiconductors, and sensors. Currents methods of fabrication employ top down processes which use extremes of temperature, pressure, and power. There...
Advances in energy technologies and electronics have typically occurred through either heightened performance or cost reduction. This dissertation explores both routes through a series of fundamental material studies that may contribute to the enabling of next generation devices. Solution based syntheses and deposition of chemical products offer a low cost...
Metal oxide clusters are promising inorganic photoresists in next generation nanomanufacturing because of their potential for high-resolution and low line-edge roughness patterning, and exceptional sensitivity to extreme ultraviolet (EUV) radiation. In EUV patterning, absorption of EUV radiation leads to electron emission that serve as a primary species for driving radiation...
Porous carbon is indispensable in modern technology applications. It is used for energy storage, gas separation, water purification, catalyst support, and chromatography. The diversity of its applications stems from its unique properties, including high specific surface area, tunable pore volume, and chemical stability. Specifically, the large surface area provides high...
Despite significant advantages in terms of portability and cost, near-infrared (NIR) gas sensing still remains a great challenge due to its relatively weak overtone absorption from the fundamental vibrational bond absorption at the mid-IR frequency. In this paper, we demonstrated ultra-sensitive NIR gas sensing for carbon dioxide (CO₂) at 1.57...
In this paper, we report a fiber-optic carbon dioxide (CO₂) near-infrared (IR) absorption sensor with only 8-cm sensing length that is coated with nanoporous metalorganic framework material Cu-BTC (BTC = benzene-1,3, 5-tricarboxylate). The multimode optical fiber was etched by hydrofluoric acid to remove the cladding and part of the core,...
Combined plasmonic nanocrystals and metal–organic framework
thin-films are fabricated for sensing gases in the near-infrared
range. This nanocomposite thin-film shows a highly sensitive response
in near-infrared absorption, which is attributed to preconcentration
of gas molecules in metal–organic framework pores causing close
proximity to the electromagnetic fields at the plasmonic nanocrystal...
Full Text:
John P. Baltrus,c Alan X. Wang*b and Chih-Hung Chang*a
Combined plasmonic nanocrystals and metal
Nanomaterials are expected to enable significant advances in several technological fields in coming years. Among them, electronics has emerged as one of the most likely benefactors from the ability to control matter on the nanometer-scale. For many electronic devices synthesized nanomaterials must be integrated into thin film structures. Vapor-based deposition...